40123-48-6Relevant academic research and scientific papers
Remote meta C-H bond functionalization of 2-phenethylsulphonic acid and 3-phenylpropanoic acid derivatives
Modak, Atanu,Mondal, Anirban,Watile, Rahul,Mukherjee, Semanti,Maiti, Debabrata
, p. 13916 - 13919 (2016)
This discovery illustrates selective meta C-H bond activation from multiple non-equivalent C-H bonds present in medicinally relevant arylethanesulfonic acid and the 2-arylpropanoic acid moiety using weakly coordinating nitrile as a directing group. Transformation of the meta olefinated compounds to important organic molecules has been demonstrated. Efforts were made to obtain mechanistic detail of the meta C-H bond functionalization reaction.
Directing-group-assisted copper-catalyzed oxidative esterification of phenols with aldehydes
Zheng, Yong,Song, Wei-Bin,Xuan, Li-Jiang
, p. 10834 - 10843 (2015/11/17)
A directing-group-assisted copper-catalyzed oxidative esterification of phenols with aldehydes using TBHP as an oxidant was described. This methodology which showed the advantages of base, ligand free, short routes and functional group tolerance could be used as an alternative protocol for the classical esterification reactions.
