40159-07-7Relevant academic research and scientific papers
THE RELATIVE REACTIVITY OF 2-METHYL-1,3-DIOXOLANE IN RADICAL REACTION WITH UNSATURATED COMPOUNDS
Ryabinina, T. A.,Kruglov, D. E.,Pastushenko, E. V.,Terent'ev, A. B.
, p. 602 - 605 (2007/10/02)
The reactivity of 2-methyl-1,3-dioxolan-2-yl radicals toward α-olefins containing substituents with various polarities was studied.There is a substantial increase in the relative addition rate constant in the series consisting of vinyl butyl ether, 1-hexene, vinyl acetate, trimethylvinylsilane, methyl acrylate, and acrylonitrile.This indicates that the 2-methyl-1,3-dioxolan-2-yl radicals have clearly defined nucleophilic character.
