Welcome to LookChem.com Sign In|Join Free
  • or

497-26-7

Post Buying Request

497-26-7 Suppliers

Recommended suppliersmore

Product FOB Price Min.Order Supply Ability Supplier
1,3-Dioxolane,2-methyl-
Cas No: 497-26-7
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
2-Methyl-1,3-dioxolane
Cas No: 497-26-7
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
TIANFU CHEM 497-26-7 2-METHYL-1,3-DIOXOLANE
Cas No: 497-26-7
No Data 1 Kilogram 1000 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
Wholesale price CAS 497-26-7 with best price
Cas No: 497-26-7
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
2-methyl-1,3-dioxolane
Cas No: 497-26-7
No Data 1 Kilogram 1 Metric Ton/Month HANGZHOU YUNUO CHEMICAL CO.,LTD Contact Supplier
2-methyl-1,3-dioxolane
Cas No: 497-26-7
No Data 2 Kilogram 150 Kilogram/Week Career Henan Chemical Co Contact Supplier
Factory Supply 2-methyl-1,3-dioxolane
Cas No: 497-26-7
No Data No Data Metric Ton/Day Ality Chemical Corporation Contact Supplier
1,3-Dioxolane,2-methyl-
Cas No: 497-26-7
No Data No Data 5 Hangzhou J&H Chemical Co., Ltd. Contact Supplier
2-Methyl-1,3-dioxolane
Cas No: 497-26-7
No Data No Data No Data Huarong Industrial Group Ltd. Contact Supplier
1,3-Dioxolane,2-methyl- CAS NO.497-26-7
Cas No: 497-26-7
No Data No Data No Data Jilin haofei import and export trade Co.,Ltd Contact Supplier

497-26-7 Usage

Chemical Properties

clear colorless liquid

Hazard

Irritant.

Uses

Extractant and solvent for oils, fats, waxes,dyestuffs, and cellulose derivatives.
InChI:InChI=1/C4H8O2/c1-4-2-3-5-6-4/h4H,2-3H2,1H3

497-26-7 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (A12824)  2-Methyl-1,3-dioxolane, 98%    497-26-7 10g 599.0CNY Detail
Alfa Aesar (A12824)  2-Methyl-1,3-dioxolane, 98%    497-26-7 50g 2285.0CNY Detail
Alfa Aesar (A12824)  2-Methyl-1,3-dioxolane, 98%    497-26-7 250g 9755.0CNY Detail
Aldrich (292206)  2-Methyl-1,3-dioxolane  97% 497-26-7 292206-5G 395.46CNY Detail
Aldrich (292206)  2-Methyl-1,3-dioxolane  97% 497-26-7 292206-25G 1,160.64CNY Detail

497-26-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Methyl-1,3-dioxolane

1.2 Other means of identification

Product number -
Other names 2-METHYL-1,3-DIOXOLANE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:497-26-7 SDS

497-26-7Synthetic route

ethylene glycol
107-21-1

ethylene glycol

acetaldehyde
75-07-0

acetaldehyde

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With chloro-trimethyl-silane at 20℃; for 0.416667h;97%
With toluene-4-sulfonic acid 1.)cooling, 1 h 2.)20 deg C, 20 h;57%
With C6H12Bi6O28S6 for 4h; Reflux;10%
ethanol
64-17-5

ethanol

ethylene glycol
107-21-1

ethylene glycol

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; sodium nitrite at 50℃; for 24h; Temperature; Time; UV-irradiation;67%
2-bromomethyl-1,3-dioxolane
4360-63-8

2-bromomethyl-1,3-dioxolane

ethyl 3-bromobenzoate
24398-88-7

ethyl 3-bromobenzoate

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

di(1,3-dioxolan-2-yl)methane
4405-17-8

di(1,3-dioxolan-2-yl)methane

C

benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

D

ethyl 3-((1,3-dioxolan-2-yl)methyl)benzoate
898776-72-2

ethyl 3-((1,3-dioxolan-2-yl)methyl)benzoate

E

3,3'-dicarbethoxybiphenyl

3,3'-dicarbethoxybiphenyl

Conditions
ConditionsYield
With pyridine; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 1,10-Phenanthroline; NiI2*3.5H2O; sodium iodide; zinc at 20 - 60℃; for 19h; chemoselective reaction;A n/a
B n/a
C n/a
D 66%
E n/a
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

lead(IV) tetraacetate
546-67-8

lead(IV) tetraacetate

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

2-ethoxyethyl acetate
111-15-9

2-ethoxyethyl acetate

C

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
In chlorobenzene at 140℃; for 0.5h;A 27%
B 63%
C 10%
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

2-ethoxyethyl acetate
111-15-9

2-ethoxyethyl acetate

C

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
With lead(IV) acetate In chlorobenzene at 140℃; for 0.5h; glass tube;A 27%
B 63%
C 10%
2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With potassium hydroxide at 120℃; Product distribution; cyclization, various alkalis;51%
With sulfuric acid
ethylene glycol
107-21-1

ethylene glycol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

1,4-dioxane
123-91-1

1,4-dioxane

C

acetaldehyde
75-07-0

acetaldehyde

D

diethylene glycol
111-46-6

diethylene glycol

Conditions
ConditionsYield
With tungsten trioxide on silica; hydrogen In water at 340℃; Temperature; Inert atmosphere;A 38.8%
B 28.7%
C 44.9%
D n/a
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

ethylene glycol monoformate
628-35-3

ethylene glycol monoformate

C

ethoxyacetaldehyde
22056-82-2

ethoxyacetaldehyde

D

formic acid ethyl ester
109-94-4

formic acid ethyl ester

Conditions
ConditionsYield
With air; methyl nitrite; nitrogen(II) oxide at 23.85℃; under 750 Torr; for 2h; Oxidation; UV-irradiation; Further byproducts given;A 3.4%
B 36%
C 24%
D 43%
ethylene glycol
107-21-1

ethylene glycol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

diethylene glycol
111-46-6

diethylene glycol

Conditions
ConditionsYield
With synthetic silica ge at 150℃; for 24h; Kinetics; Autoclave; Green chemistry;A 40%
B 9%
ethylene glycol
107-21-1

ethylene glycol

acetylene
74-86-2

acetylene

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

ethylene glycol divinyl ether
764-78-3

ethylene glycol divinyl ether

C

2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

Conditions
ConditionsYield
With sodium hydroxide; cesium fluoride at 138 - 142℃; under 10297.1 Torr; for 3.5h;A 4%
B 11%
C 26%
ethylene glycol
107-21-1

ethylene glycol

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With silica gel In neat (no solvent) at 150℃; under 1147.61 Torr; for 7h; Autoclave;19%
With silica gel at 150℃; for 7h; Kinetics; Reagent/catalyst; Autoclave; Green chemistry;19%
tetrachloromethane
56-23-5

tetrachloromethane

2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-(ethoxyethoxy)-ethanol
65850-74-0

2-(ethoxyethoxy)-ethanol

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
at 210℃;
vinyl acetate
108-05-4

vinyl acetate

ethylene glycol
107-21-1

ethylene glycol

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; mercury(II) oxide
-butyl vinyl ether
111-34-2

-butyl vinyl ether

ethylene glycol
107-21-1

ethylene glycol

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With hydrogenchloride
ethylene glycol
107-21-1

ethylene glycol

(E)-3-Ureido-but-2-enoic acid ethyl ester
5435-44-9, 22243-66-9

(E)-3-Ureido-but-2-enoic acid ethyl ester

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

1,4-dioxane
123-91-1

1,4-dioxane

C

acetaldehyde
75-07-0

acetaldehyde

ethylene glycol
107-21-1

ethylene glycol

acetylene
74-86-2

acetylene

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

ethylene glycol
107-21-1

ethylene glycol

paracetaldehyde
123-63-7

paracetaldehyde

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With sulfuric acid at 100℃;
With cation exchanger Unter Entfernen des entstehenden Wassers;
1,2-bis-(1-chloro-ethoxy)-ethane
89583-60-8

1,2-bis-(1-chloro-ethoxy)-ethane

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

ethylene glycol divinyl ether
764-78-3

ethylene glycol divinyl ether

Conditions
ConditionsYield
With N,N-diethylaniline
2,3-dihydroxy-1,4-dioxane
4845-50-5

2,3-dihydroxy-1,4-dioxane

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

1,4-dioxene
543-75-9

1,4-dioxene

Conditions
ConditionsYield
With toluene-4-sulfonic acid 1.) ethylene glycol, 100 deg C, 15 min; 2.) ethylene glycol; Multistep reaction;
2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

propane
74-98-6

propane

E

potassium acetate
127-08-2

potassium acetate

F

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With potassium hydroxide at 170℃; Product distribution; other hydroxides (Na, Li);
2-[2-(ethenyloxy)ethoxy]ethan-1-ol
929-37-3

2-[2-(ethenyloxy)ethoxy]ethan-1-ol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

ethanol
64-17-5

ethanol

C

2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

Conditions
ConditionsYield
With potassium hydroxide at 170 - 250℃; Product distribution;
carbon monoxide
201230-82-2

carbon monoxide

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

ethanol
64-17-5

ethanol

C

acetaldehyde
75-07-0

acetaldehyde

D

formic acid ethyl ester
109-94-4

formic acid ethyl ester

Conditions
ConditionsYield
With hydrogen; Co(CO)8 In various solvent(s) at 200℃; under 237880 Torr; for 6h; Further byproducts given. Title compound not separated from byproducts;A 7 mmol
B 45 mmol
C 3 mmol
D 20 mmol
ethylene glycol
107-21-1

ethylene glycol

acetone
67-64-1

acetone

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

2,2-dimethyl-1,3-dioxolane
2916-31-6

2,2-dimethyl-1,3-dioxolane

C

diethyl acetal
105-57-7

diethyl acetal

D

ethanol
64-17-5

ethanol

E

acetaldehyde
75-07-0

acetaldehyde

F

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With hydrogenchloride for 30h; Product distribution; Irradiation; reaction without aq. HCl;
ethylene glycol
107-21-1

ethylene glycol

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

C

2-hydroxymethyl-1,3-dioxolane
5694-68-8

2-hydroxymethyl-1,3-dioxolane

D

formic acid
64-18-6

formic acid

E

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With iron(III)-acetylacetonate; oxygen In water at 150℃; for 100h; Product distribution; other acetloacetonates, also in basic solution;
ethylene glycol
107-21-1

ethylene glycol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

1,4-dioxane
123-91-1

1,4-dioxane

C

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With Nafion-H at 175℃; for 19h; Product distribution; also in continuous flow reactor charged with Nafion-H or NaHX zeolites, at 175 deg C or 250 deg C, respectively;A 20 % Chromat.
B 71 % Chromat.
C 6 % Chromat.
With sulfuric acid In water at 110 - 140℃; Product distribution; Dehydration; cyclization;
diethylene glycol
111-46-6

diethylene glycol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

1,4-dioxane
123-91-1

1,4-dioxane

C

1,4-dioxene
543-75-9

1,4-dioxene

D

p-dioxanone
3041-16-5

p-dioxanone

Conditions
ConditionsYield
With zeolite NaY; copper at 280℃; further catalysts and conditions; Yield given;
With zeolite NaY; copper at 280℃; Product distribution; effect of support on selectivity of dioxene formation; further catalysts and conditions;
1,1-dimethoxyethane
534-15-6

1,1-dimethoxyethane

ethylene glycol
107-21-1

ethylene glycol

A

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

B

methanol
67-56-1

methanol

C

acetaldehyde-[bis-(2-hydroxy-ethyl)-acetal]
78706-61-3

acetaldehyde-[bis-(2-hydroxy-ethyl)-acetal]

D

2-(1-methoxy-ethoxy)-ethanol

2-(1-methoxy-ethoxy)-ethanol

Conditions
ConditionsYield
In dimethylsulfoxide-d6 at 25℃; for 24h; Product distribution; Further Variations:; reagent ratios; transacetalization;
acetaldehyde
75-07-0

acetaldehyde

ethylene glycol (excess)

ethylene glycol (excess)

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

methyl 3-(2-methyl-1,3-dioxolan-2-yl)butanoate
1332861-28-5

methyl 3-(2-methyl-1,3-dioxolan-2-yl)butanoate

Conditions
ConditionsYield
With (Bu4N)2S2O8 In 1,2-dichloro-ethane at 70℃; for 2.5h; Inert atmosphere; regioselective reaction;99%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

ethylene glycol
107-21-1

ethylene glycol

Conditions
ConditionsYield
With water under 76.0051 - 760.051 Torr; Reflux;99%
With water; silica gel In neat (no solvent) at 150℃; under 1147.61 Torr; for 24h; Autoclave;10%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-bromomethyl-1,3-dioxolane
4360-63-8

2-bromomethyl-1,3-dioxolane

Conditions
ConditionsYield
With bromine; di-tert-butyldicyclohexano-18-crown-18 In benzene at 20℃; for 0.166667h; Bromination;96%
With 1,4-Dioxane Dibromide In tetrachloromethane at 29.9℃; Rate constant; Thermodynamic data; Mechanism; ΔH(excit.), ΔS(excit.), ΔG(excit.), lg A; further temp., kinetics;
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

dimethyl cis-but-2-ene-1,4-dioate
624-48-6

dimethyl cis-but-2-ene-1,4-dioate

2-(2-methyl-1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester
102277-14-5

2-(2-methyl-1,3-dioxolan-2-yl)butanedioic acid 1,4-dimethyl ester

Conditions
ConditionsYield
With (Bu4N)2S2O8 In 1,2-dichloro-ethane at 70℃; for 0.333333h; Inert atmosphere; regioselective reaction;96%
With di-tert-butyl peroxide at 20℃; for 0.5h; Inert atmosphere; UV-irradiation;95%
With di-tert-butyl peroxide at 20℃; under 50 Torr; for 3h; Sonication; Inert atmosphere; Photolysis;
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

N-(4-acetylamino-phenyl)-glycine ethyl ester
183889-12-5

N-(4-acetylamino-phenyl)-glycine ethyl ester

C16H22N2O5

C16H22N2O5

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;92%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

Conditions
ConditionsYield
With 3,3-dimethyldioxirane In acetone at 25℃; Kinetics;91%
With 3,3-dimethyldioxirane In acetone at 25℃;91%
With dinitrogen tetraoxide at 0℃; for 2h; var. reag.: O2 with Co(II)salt and 18-crown-6; O3 or hydroperoxides;84%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

(5S)-5-(tert-butyldimethylsilanyloxymethyl)-5H-furan-2-one
105122-15-4

(5S)-5-(tert-butyldimethylsilanyloxymethyl)-5H-furan-2-one

5-O-(tert-butyldimethylsilyloxymethyl)-4-C-(2-methyl-1,3-dioxolane)-tetrahydrofuran-2-one
1370642-61-7

5-O-(tert-butyldimethylsilyloxymethyl)-4-C-(2-methyl-1,3-dioxolane)-tetrahydrofuran-2-one

Conditions
ConditionsYield
With benzophenone for 2h; Inert atmosphere;87%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

(S)-methyl 3-methyl-2-(2-(phenylamino)acetamido)butanoate

(S)-methyl 3-methyl-2-(2-(phenylamino)acetamido)butanoate

C18H26N2O5

C18H26N2O5

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;85%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Ph-Gly-Pro-Val-OMe

Ph-Gly-Pro-Val-OMe

C23H33N3O6

C23H33N3O6

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;85%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

C16H21NO5

C16H21NO5

C20H27NO7

C20H27NO7

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;84%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Ph-Gly-Ala-OBn

Ph-Gly-Ala-OBn

C22H26N2O5

C22H26N2O5

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;84%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

ethyl 2,3-dideoxy-6-O-trityl-α-D-glycero-hex-2-enopyranosid-4-ulose
40555-08-6

ethyl 2,3-dideoxy-6-O-trityl-α-D-glycero-hex-2-enopyranosid-4-ulose

(2R,5S,6S)-6-Ethoxy-5-(2-methyl-[1,3]dioxolan-2-yl)-2-trityloxymethyl-dihydro-pyran-3-one

(2R,5S,6S)-6-Ethoxy-5-(2-methyl-[1,3]dioxolan-2-yl)-2-trityloxymethyl-dihydro-pyran-3-one

Conditions
ConditionsYield
With trans-di-O-tert-butyl hyponitrite In acetonitrile for 1h; Heating; other substrates, other reactants;83%
With trans-di-O-tert-butyl hyponitrite In acetonitrile for 1h; Heating;83%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

methyl vinyl ketone
78-94-4

methyl vinyl ketone

A

(2-methyl-[1,3]dioxolan-2-yl)-acetic acid
5735-97-7

(2-methyl-[1,3]dioxolan-2-yl)-acetic acid

B

3,3-ethylenedioxybutanal
18871-63-1

3,3-ethylenedioxybutanal

Conditions
ConditionsYield
With oxygen; N-hydroxyphthalimide; cobalt(II) acetate at 25℃;A 83%
B 4%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

bis(diethylamino)chlorophosphine
685-83-6

bis(diethylamino)chlorophosphine

(1-(2-chloroethoxy)ethyl)phosphonic acid bis(diethylamide)

(1-(2-chloroethoxy)ethyl)phosphonic acid bis(diethylamide)

Conditions
ConditionsYield
With zinc trifluoromethanesulfonate In tetrahydrofuran at 130℃; for 24h; Microwave irradiation; Inert atmosphere; Sealed tube;83%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

Methyl (+/-)-2-hydroxy-3-(2-methyl-1,3-dioxolan-2-yl)propanoate
163458-23-9

Methyl (+/-)-2-hydroxy-3-(2-methyl-1,3-dioxolan-2-yl)propanoate

Conditions
ConditionsYield
With N-hydroxyphthalimide; oxygen; cobalt(II) acetate at 20℃; for 3h;81%
With oxygen; N-hydroxyphthalimide; cobalt(II) acetate at 25℃; for 3h;81%
With 4,9-(benzene-1,2-diyl)-2,4-dihydroxy-3a,4,9,9a-tetrahydro-1H-benzo[f]isoindole-1,3(2H)-dione; oxygen; cobalt(II) acetate at 20℃; under 760.051 Torr; for 5h;60%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

4-benzyl-3-(tert-butylperoxy)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

4-benzyl-3-(tert-butylperoxy)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

4-benzyl-3-(2-methyl-1,3-dioxolan-2-yl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

4-benzyl-3-(2-methyl-1,3-dioxolan-2-yl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-2-one

Conditions
ConditionsYield
With copper diacetate In 1,2-dichloro-ethane at 60℃; for 6h; Inert atmosphere;81%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

A

1,2-ethanediol acetate formate
29776-97-4

1,2-ethanediol acetate formate

B

ethylene glycol mono caprylate
4219-47-0

ethylene glycol mono caprylate

Conditions
ConditionsYield
With oxygen; zinc(II) chloride; CoCl2 In 1,2-dimethoxyethane at 55℃; for 41h;A 79%
B 80%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

diethyl Fumarate
623-91-6

diethyl Fumarate

(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester
60636-60-4

(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester

Conditions
ConditionsYield
With N-hydroxyphthalimide; dibenzoyl peroxide In toluene at 80℃; for 1h;80%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-Cyclohepten-1-one
1121-66-0

2-Cyclohepten-1-one

C11H18O3
1332861-29-6

C11H18O3

Conditions
ConditionsYield
With (Bu4N)2S2O8 In 1,2-dichloro-ethane at 70℃; for 1.5h; Inert atmosphere; regioselective reaction;80%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

N-phenylglycine ethyl ester
2216-92-4

N-phenylglycine ethyl ester

C14H19NO4

C14H19NO4

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Catalytic behavior; Reagent/catalyst; Inert atmosphere;80%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

cyclopent-2-enone
930-30-3

cyclopent-2-enone

3-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

3-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

Conditions
ConditionsYield
With benzophenone In acetonitrile for 2.5h; Irradiation;78%
With (Bu4N)2S2O8 In 1,2-dichloro-ethane at 70℃; for 0.5h; Inert atmosphere; regioselective reaction;60%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

acrylonitrile
107-13-1

acrylonitrile

2-hydroxy-3-(2-methyl-1,3-dioxolan-2-yl)propanenitrile

2-hydroxy-3-(2-methyl-1,3-dioxolan-2-yl)propanenitrile

Conditions
ConditionsYield
With oxygen; N-hydroxyphthalimide; cobalt(II) acetate at 25℃; for 16h;77%
With 4,9-(benzene-1,2-diyl)-2,4-dihydroxy-3a,4,9,9a-tetrahydro-1H-benzo[f]isoindole-1,3(2H)-dione; oxygen; cobalt(II) acetate at 20℃; under 760.051 Torr;58%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

norbornene
498-66-8

norbornene

diethyl Fumarate
623-91-6

diethyl Fumarate

A

(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester
60636-60-4

(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester

2-(1R,2R,4S)-Bicyclo[2.2.1]hept-2-yl-3-(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester

2-(1R,2R,4S)-Bicyclo[2.2.1]hept-2-yl-3-(2-methyl-[1,3]dioxolan-2-yl)-succinic acid diethyl ester

Conditions
ConditionsYield
With N-hydroxyphthalimide; dibenzoyl peroxide In toluene at 80℃; for 15h;A 12%
B 77%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

benzophenone
119-61-9

benzophenone

(+/-)-trans-3-hydroxy-4-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

(+/-)-trans-3-hydroxy-4-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

(+/-)-cis-3-hydroxy-4-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

(+/-)-cis-3-hydroxy-4-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

(2SR,3RS,4RS)-4-hydroxy-2-(diphenylhydroxymethyl)-3-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

(2SR,3RS,4RS)-4-hydroxy-2-(diphenylhydroxymethyl)-3-(2-methyl-1,3-dioxolan-2-yl)cyclopentanone

Conditions
ConditionsYield
In acetonitrile for 2h; Irradiation;A 75%
B n/a
C 7.5%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Ph-Gly-Pro-Phe-Val-OMe

Ph-Gly-Pro-Phe-Val-OMe

C32H42N4O7

C32H42N4O7

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;75%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Eto-Gly-Phe-Gly-oet

Eto-Gly-Phe-Gly-oet

C19H26N2O7

C19H26N2O7

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;75%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

Benzylidenemalononitrile
2700-22-3

Benzylidenemalononitrile

2-((2-methyl-1,3-dioxolan-2-yl)(phenyl)methyl)malononitrile

2-((2-methyl-1,3-dioxolan-2-yl)(phenyl)methyl)malononitrile

Conditions
ConditionsYield
With pyrene-1,6-dione at 50℃; for 24h; Irradiation;75%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-methyl-2-(2-(phenylsulfonyl)ethyl)-1,3-dioxolane
56161-54-7

2-methyl-2-(2-(phenylsulfonyl)ethyl)-1,3-dioxolane

Conditions
ConditionsYield
With tetrabutylammonium decatungstate ammonium salt; sodium hydrogencarbonate In acetonitrile for 20h; Catalytic behavior; Reagent/catalyst; Solvent; UV-irradiation; Inert atmosphere;74%
With (Bu4N)2S2O8 In 1,2-dichloro-ethane at 70℃; for 1.5h; Inert atmosphere; regioselective reaction;48%
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

C15H19NO5

C15H19NO5

C19H25NO7

C19H25NO7

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper (I) acetate In water; 1,2-dichloro-ethane at 60℃; for 16h; Inert atmosphere;74%

Please post your buying leads,so that our qualified suppliers will soon contact you!

*Required Fields