4016-14-2 Usage
Chemical Properties
colourless liquid
Uses
Different sources of media describe the Uses of 4016-14-2 differently. You can refer to the following data:
1. Glycidyl isopropyl ether is a stabilizer of chlorinated solvents, and viscosity reducer of epoxy resins.
2. Isopropyl glycidyl ether (IGE) is used to sta-bilize chlorinated solvents and as a viscosityreducer of epoxy resins.
3. Reactive diluent for epoxy resins;
stabilizer for organic compounds; chemical
intermediate for synthesis of ethers and esters
Production Methods
Isopropyl glycidyl ether is manufactured through the condensation
of isopropyl alcohol and epichlorohydrin with
subsequent dehydrochlorination with caustic to form the
epoxy ring.
General Description
Colorless liquid.
Air & Water Reactions
Highly flammable. Water soluble.
Reactivity Profile
Ethers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Hazard
Flammable liquid with flash p 92F
(33.33C). Skin, eye and respiratory tract irritant.
Health Hazard
Different sources of media describe the Health Hazard of 4016-14-2 differently. You can refer to the following data:
1. IGE is a skin and eye irritant with lowtoxicity. Irritation in rabbits’ eyes and skincaused by 100 mg was moderate to low.In humans, frequent skin contact may causedermatitis.Studies on rats indicated low toxicity ofthis compound with symptoms of respiratorydistress. Prolonged exposure caused ocularirritation and depression of the central ner-vous system. An increase in hemoglobin anda decrease in peritoneal fat was observed.
2. Exposure can cause mental confusion and moderate irritation of the eyes, skin, and respiratory tract. Chronic exposure can cause dermatitis and skin sensitization.
Fire Hazard
Flammable; flash point (closed cup) 33°C
(92°F); vapor pressure 9.4 torr at 25°C
(77°F); forms explosive mixtures with air,
LEL and UEL values not reported; fire-
extinguishing agent: use a water spray to
extinguish fire.
Check Digit Verification of cas no
The CAS Registry Mumber 4016-14-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,0,1 and 6 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 4016-14:
(6*4)+(5*0)+(4*1)+(3*6)+(2*1)+(1*4)=52
52 % 10 = 2
So 4016-14-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H12O2/c1-5(2)7-3-6-4-8-6/h5-6H,3-4H2,1-2H3/t6-/m1/s1
4016-14-2Relevant articles and documents
Complexes of cyclic polyaza chelators with cations of alkaline earth metals for enhanced biological activity
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Page/Page column 7, (2010/02/11)
Cyclic polyaza chelators that possess high affinity and specificity for first transition series metal cations exhibit an unanticipated improvement in biological activity when administered as complexes with cations of the alkaline earth metals, Ca(II) and Mg(II), most notably Ca(II). By virtue of this improvement, these complexes are particularly effective in the treatment of pathological conditions, including ischemia and ischemia-reperfusion injury.
Synthesis and Insecticidal Activity of Oxazaphospholidines, Oxathiaphospholanes, and Thiazaphospholidines
Wu, Shao-Yong,Hirashima, Akinori,Takeya, Ryuko,Eto, Morifusa
, p. 2911 - 2918 (2007/10/02)
Fifty-five new five-membered cyclic organophosphorus compounds including oazaphospholidines, thiazaphospholidines, and oxathiaphospholanes were synthesized, which have substituents at 4- or/and 5-positions besides at the 2-position.The thiazaphospholidines showed the highest insecticidal activity followed by oxathiaphospholanes and oxazaphospholidines.The position preference of substituents in insecticidal activity was most obvious in the oxazaphospholidines.It was preferable for insecticidal activity to have the substituent near the more basic atom: the 4-position for thiazaphospholidine and oxazaphospholidine, the 5-position for oxathiaphospholane, with the exception of 4- or 5-phenyl oxazaphospholidine.