40164-27-0Relevant academic research and scientific papers
Heats of Hydrogenation of Some Vinyl Ethers and Related Compounds
Allinger, N. L.,Glaser, John A.,Davis, H. E.,Rogers, Donald W.
, p. 658 - 661 (1981)
The heats of hydrogenation of a number of vinyl ethers and related compounds have been measured in hexane solution.The presence of the oxygen has a small to moderate effect on the magnitudes of these numbers, depending on the situation, and may either stabilize or destabilize the double bonds relative to the hydrogenation products.The results can, in the main, be interpreted in a straightforward way using resonance and induction arguments.
Transformation of hydroxycycloalkanones to oxabicycloalkenes
Kraemer, Guido,Detert, Heiner,Meier, Herbert
scheme or table, p. 2201 - 2208 (2010/04/29)
Oxabicycloalkenes, which represent anti-Bredt enol ethers, can be generated by catalytic dehydration of the hemiacetals of hydroxycycloalkanones (Method I). Another option is provided by the transformation of hydroxycycloalkanones to the corresponding 1,2,3-selenadiazoles and their thermal fragmentation on Cu powder (Method II). The intermediate hydroxycycloalkynes show a transannular addition of the OH group to the triple bond. Altogether seven new oxabicycloalk-1-enes were obtained by this methods.
