37996-41-1

Basic information

• Product Name: 9-oxabicyclo[3.3.1]nonan-1-ol
• Synonyms: 9-oxabicyclo[3.3.1]nonan-1-ol
• CAS NO: 37996-41-1
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 142.19556
• Mol File: 37996-41-1.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 9-oxabicyclo[3.3.1]nonan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 9-oxabicyclo[3.3.1]nonan-1-ol(37996-41-1)
• EPA Substance Registry System: 9-oxabicyclo[3.3.1]nonan-1-ol(37996-41-1)

Safety Data

• Hazardous Substances Data: 37996-41-1(Hazardous Substances Data)

Upstream product

• 1552-12-1 1,5-cis,cis-cyclooctadiene 
• 23418-82-8 cis-1,5-cyclooctanediol 
• 1489-74-3 cyclooctane-1,5-dione 
• 98560-11-3 tetrahydro-6-(3-iodopropyl)-2H-pyran-2-one 
• 82390-99-6 1-(2,4-dinitrophenoxy)-9-oxabicyclo<3.3.1>nonane 
• 55343-44-7 cyclooctane-1,5-diol 
• 54623-44-8 5-(3-Bromopropyl)-5-pentanolide 
• 4103-12-2 5-bromocyclooct-1-ene 
• 54529-99-6 5-acetoxy-6-acetoxymercuriacyclo-octene 
• 292-64-8 Cyclooctan 

Downstream Products

• 34958-37-7 5-Hydroxycyclooctanon-p-toluolsulfonat 
• 40164-27-0 9-Oxabicyclo<3.3.1>non-1-en 
• 3301-94-8 6-Butyl-tetrahydro-pyran-2-one 
• 70470-06-3 N-methylanatoxin 
• 70423-78-8 9-methyl-9-azabicyclo[4.2.1]nonan-2-one 
• 19860-84-5 Toluene-4-sulfonic acid (Z)-5-methyl-cyclooct-4-enyl ester 
• 82390-99-6 1-(2,4-dinitrophenoxy)-9-oxabicyclo<3.3.1>nonane 
• 37757-45-2 4-oxosuberic acid 

Relevant articles and documents

A Very Large Stereoelectronic Effect on Acetal Cleavage

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Conformationally restricted nonchiral pipecolic acid analogues

(Chemical Equation Presented) Practical syntheses of 2-azabicyclo[3.1.1] heptane-1-carboxylic (2,4-methanopipecolic), 2-azabicyclo [2.2.2]octane-1- carboxylic (2,5-ethanopipecolic), and 9-azabicyclo[3.3.1]nonane-1-carboxylic (2,6-propanopipecolic) acids a

Intramolecular C-H insertion reactions of (η5-Cyclopentadienyl)dicarbonyliron carbene complexes: Scope of the reactions and application to the synthesis of (±)-sterpurene and (±)-pentalenene

(η5-Cyclopentadienyl)dicarbonyliron carbene complexes, [(η5C5H5) (CO)2Fe=CHR]+BF4-, are generated as reactive intermediates from thioether derivatives, (η5-C5H5)(CO)2FeCH(R)SPh, by S-alkylation with trimethyloxonium tetrafluoroborate and loss of thioanisole. The carbene complexes undergo intramolecular C-H insertion into appropriately situated side chains to form cyclopentane derivatives. The reaction has been developed into a general procedure employing cycloalkanones as scaffolds bearing the iron carbene moieties and the side chains at C(2) and C(3), respectively. The products of the intramolecular insertion reactions are substituted bicyclo[n.3.0]alkanones. The scope and limitations of the reaction are described. The reaction is applied to a total synthesis of sterpurene and to a formal synthesis of pentalenene. Overall, this approach to cyclopentane annulation complements the related metal-catalyzed insertion reactions of diazocarbonyl compounds, which are also believed to occur via metal carbene complexes.