401895-10-1Relevant academic research and scientific papers
Synthesis of sporochnol A, a marine fish deterrent
Biswas, Bidyut,Venkateswaran, Ramanthapuram V.
, p. 1769 - 1779 (2007/10/03)
A synthesis of the methyl ether of the fish-deterrent sporochnol A is described. The route involves the application of Claisen ortho-ester rearrangement to generate the key quaternary carbon. Copyright Taylor & Francis, Inc.
Total synthesis of sporochnols, fish deterrents from a marine alga
Ohira, Susumu,Kuboki, Atsuhito,Hasegawa, Taisuke,Kikuchi, Takato,Kutsukake, Tatsuhiko,Nomura, Maki
, p. 4641 - 4644 (2007/10/03)
Sporochnols, fish deterrents from a marine alga, were synthesized, using intramolecular C-H insertion of alkylidenecarbene as a key step to construct the chiral quaternary center.
Employment of a cyclobutene ring-opening metathesis reaction towards a concise synthesis of (±)-sporochnol A
Bassindale, Martin J.,Hamley, Peter,Harrity, Joseph P.A
, p. 9055 - 9057 (2007/10/03)
A concise formal synthesis of (±)-sporochnol A 1, a naturally occurring feeding deterrent towards herbivorous fish, is described. The target compound was prepared by the employment of a Ru-catalysed cyclobutene ring-opening metathesis reaction with gaseou
