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402507-42-0

[Cu(2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine)(THF)(CH3CN)]PF6 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 402507-42-0 Structure

  • Basic information

    1. Product Name: [Cu(2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine)(THF)(CH3CN)]PF6
    2. Synonyms:
    3. CAS NO:402507-42-0
    4. Molecular Formula:
    5. Molecular Weight: 803.394
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 402507-42-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [Cu(2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine)(THF)(CH3CN)]PF6(CAS DataBase Reference)
    10. NIST Chemistry Reference: [Cu(2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine)(THF)(CH3CN)]PF6(402507-42-0)
    11. EPA Substance Registry System: [Cu(2,6-bis(1-(2,6-diisopropylphenylimino)ethyl)pyridine)(THF)(CH3CN)]PF6(402507-42-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 402507-42-0(Hazardous Substances Data)

402507-42-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 402507-42-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,0,2,5,0 and 7 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 402507-42:
(8*4)+(7*0)+(6*2)+(5*5)+(4*0)+(3*7)+(2*4)+(1*2)=100
100 % 10 = 0
So 402507-42-0 is a valid CAS Registry Number.

402507-42-0Relevant articles and documents

Unexpected behaviour of copper(I) towards a tridentate Schiff base: Synthesis, structure and properties of new Cu(I)-Cu(II) and Cu(II) complexes

Le Gall, Benot,Conan, Fran?oise,Cosquer, Nathalie,Kerbaol, Jean-Michel,Kubicki, Marek M.,Vigier, Estelle,Le Mest, Yves,Sala Pala, Jean

, p. 300 - 308 (2001)

The reaction of CuBr with 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine L afforded a new Cu(I)-Cu(II) derivative [CuBrL]2[Cu2Br4] (1), while the reaction of [Cu(CH3CN)4]PF6 with L in THF yielded the new Cu(I) compound CuL(THF)(CH3CN)PF6 (2). Derivative 2 further reacted with halogenated solvents to yield halogeno-Cu(II) salts, [CuClL]PF6 (3) using CHCl3 and [CuBrL]Br3 (4) using CHBr3. Compounds 1, 3 and 4 have been fully characterised by X-ray crystallography; they contain essentially similar [CuXL]+ cations with a square planar copper(II) co-ordination. However, the structure of compound 1 must be viewed as built of tetranuclear units since two [CuIIBrL]+ cations are bridged by a [Cu2IBr4]2- anion with a rather strong CuII···Br (2.689(2) A?) secondary interaction. These secondary interactions (CuII cation···FPF5 or Br anion) are weaker in 3 and 4. The electrochemical properties of compounds 1-4 are discussed, too.

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