402759-03-9Relevant academic research and scientific papers
2,3-Anhydro sugars in glycoside bond synthesis. Highly stereoselective syntheses of oligosaccharides containing α- and β-arabinofuranosyl linkages
Gadikota, Rajendrakumar Reddy,Callam, Christopher S.,Wagner, Timothy,Del Fraino, Brian,Lowary, Todd L.
, p. 4155 - 4165 (2007/10/03)
The ever-increasing discovery of biologically important events mediated by carbohydrates has generated great interest in the synthesis of oligosaccharides and the development of new methods for glycosidic bond formation. In this paper, we report that 2,3-
Arabinofuranosides from mycobacteria: Synthesis of a highly branched hexasaccharide and related fragments containing β-arabinofuranosyl residues
Yin, Haifeng,D'Souza, Francis W.,Lowary, Todd L.
, p. 892 - 903 (2007/10/03)
The synthesis of 11 oligosaccharides (4-14) containing β-arabinofuranosyl residues is reported. The glycans are all fragments of two polysaccharides, arabinogalactan and lipoarabinomannan, which are found in the cell wall complex of mycobacteria. In the preparation of the targets, the key step was a low-]temperature glycosylation reaction that installed the β-arabinofuranosyl residues with good to excellent stereocontrol.
