20194-18-7

Basic information

• Product Name: SODIUM BENZYLOXIDE
• Synonyms: SODIUM BENZYLOXIDE;SODIUM BENZYLOXIDE, 1.0M SOLUTION IN BEN;Benzenemethanol, sodium salt;sodium benzyloxide solution;Sodium benzyloxide, 1M solution in benzyl alcohol, AcroSeal;Sodium benzyloxide solution 1.0 M in benzyl alcohol;sodium:phenylmethanolate
• CAS NO: 20194-18-7
• Molecular Formula: C₇H₇NaO
• Molecular Weight: 130.12
• Product Categories: Metal and Ceramic Science;Salts;Sodium Salts
• Mol File: 20194-18-7.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 203-205 °C
• Flash Point: 194 °F
• Appearance: Clear colorless to yellow/Viscous Liquid
• Density: 1.077 g/mL at 25 °C
• CAS DataBase Reference: SODIUM BENZYLOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: SODIUM BENZYLOXIDE(20194-18-7)
• EPA Substance Registry System: SODIUM BENZYLOXIDE(20194-18-7)

Safety Data

• Hazard Codes: C
• Statements: 20/21/22-34-20/22
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3267 8/PG 2
• WGK Germany: 1
• Hazardous Substances Data: 20194-18-7(Hazardous Substances Data)

Usage

Uses

This is the sodium salt form of Benzenemethanol. Sodium Benzyloxide is used to desulfurize coal.

Upstream product

• 100-51-6 benzyl alcohol 

Downstream Products

• 57568-99-7 (Z)-2-(Acetyl-benzyloxy-amino)-but-2-enoic acid tert-butyl ester 
• 57569-00-3 (Z)-2-(Acetyl-benzyloxy-amino)-pent-2-enoic acid tert-butyl ester 
• 14593-43-2 benzyl allyl ether 
• 71516-48-8 2-((benzyloxy)methyl)-1,3-dioxolane 
• 91970-62-6 benzyl 4-hydroxybutanoate 
• 76509-17-6 3-benzyloxypyridine 
• 117068-71-0 2-(benzyloxy)-6-bromopyridine 
• 110320-68-8 methyl 2-benzyloxyhexanoate 
• 110298-77-6 α-Benzyloxyhydrozimtsaeuremethylester 
• 83081-34-9 5-Benzyloxy-2-phenyl-4-(trifluormethyl)thiazol 
• 4049-39-2 4-benzyloxy-3-hydroxy-benzaldehyde 
• 6972-79-8 dibenzyl glycerol 
• 69520-20-3 (E)-1-Phenyl-2-(phenylmethoxy)ethene 
• 83049-74-5 4-Benzyloxy-2,5-dimethyl-4,5-dihydro-oxazole-4-carboxylic acid tert-butyl ester 

Relevant articles and documents

Four- and Five-Coordinate Titanium(IV) Complexes Supported by the dpp-bian Ligand in ROP of L-Lactide

A titanium(IV) alkoxido complex, (dpp-bian)Ti(OBn)2 (2), as well as alkoxido chlorido complexes (dpp-bian)TiCl(OCH2CH2OMe) (3) and (dpp-bian)TiCl2OBn (4), were synthesized from the titanium(IV) dichloride precursor [(dpp-bian)TiCl2]2 (1) by exchange with corresponding sodium salts (comps. 2 and 3) or by the alcoholysis with BnOH (comp. 4). The compounds 2–4 were fully characterized by elemental analysis, NMR or EPR, and IR spectroscopy. Molecular structures of the metal complexes in the solid state have been determined by single-crystal XRD analysis. Compounds 2–4 were tested as catalysts in the ROP of L-lactide in a toluene medium. Whereas complexes 2 and 3 produce cyclic PLAs with broad dispersities and unpredictable molecular weights, complex 4 acts as an efficient ROP catalyst which polymerizes the monomer in a highly controllable manner. It produces BnO-capped PLAs with narrow molecular weight distributions as well as linear dependence of Mns on monomer conversion.

INHIBITORS OF THE PD-1/PD-L1 PROTEIN/PROTEIN INTERACTION

The present invention provides novel compounds of formula (I) that are useful as inhibitors of the PD-1/PD-L1 protein/protein interaction.

Solubility of sodium sulfide in alcohols

The solubility of sodium sulfide in methanol, ethanol, 2-propanol, 2-methyl-1-propanol, and benzyl alcohol and the acid-base interaction of these compounds have been determined at (20 and 35) °C. The reactions result in the formation of sodium alkoxide and hydrosulfide. The reported values on the solubility of sodium sulfide in alcohols differ essentially from the data described in the literature.