402759-08-4Relevant academic research and scientific papers
β-selective arabinofuranosylation using a 2,3-o-xylylene-protected donor
Imamura, Akihiro,Lowary, Todd L.
supporting information; experimental part, p. 3686 - 3689 (2010/11/04)
Reported is a novel stereoselective β-arabinofuranosylation that makes use of a conformationally restricted 2,3-O-xylylene-protected arabinofuranosyl donor. Optimization of the reaction conditions showed that factors including the structure of the accepto
Arabinofuranosides from mycobacteria: Synthesis of a highly branched hexasaccharide and related fragments containing β-arabinofuranosyl residues
Yin, Haifeng,D'Souza, Francis W.,Lowary, Todd L.
, p. 892 - 903 (2007/10/03)
The synthesis of 11 oligosaccharides (4-14) containing β-arabinofuranosyl residues is reported. The glycans are all fragments of two polysaccharides, arabinogalactan and lipoarabinomannan, which are found in the cell wall complex of mycobacteria. In the preparation of the targets, the key step was a low-]temperature glycosylation reaction that installed the β-arabinofuranosyl residues with good to excellent stereocontrol.
