402827-26-3

Upstream product

• 221290-57-9 [(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-acetaldehyde 

Downstream Products

• 402827-29-6 tert-butyl-{(1R)-1-([(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methylcyclohex-2-enyl]methyl)but-3-enyloxy}diphenylsilane 
• 402827-31-0 (1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-ene-1-carbaldehyde 
• 402827-41-2 {(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}methanol 
• 402827-64-9 {(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}acetaldehyde 
• 402827-45-6 {(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}acetonitrile 
• 402827-43-4 methanesulfonic acid {(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}methyl ester 
• 402827-32-1 (2R)-1-{(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}pent-4-en-2-ol 
• 402827-34-3 acetic acid (4R,4aR,6R,11R,12aR)-11-(tert-butyl(diphenyl)silanyloxy)-4-isopropyl-1-methyl-3,4,4a,5,6,7,10,11,12,12a-decahydrobenzocyclodecen-6-yl ester 
• 402827-33-2 acetic acid (1R)-1-[{(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}methyl]but-3-enyl ester 
• 503071-57-6 (4R,4aR,11R,12aR)-11-(tert-butyl(diphenyl)silanyloxy)-4-isopropyl-1-methyl-3,4a,5,7,10,11,12,12a-octahydro-4H-benzocyclodecen-6-one 
• 503071-60-1 (1R,4aR,6R,12aR)-tert-butyl(1-isopropyl-4-methyl-11-methylene-1,2,4a,5,6,7,10,11,12,12a-decahydrobenzocyclodecen-6-yloxy)diphenylsilane 
• 503071-56-5 (4R,4aR,6R,11R,12aR)-11-(tert-butyl(diphenyl)silanyloxy)-4-isopropyl-1-methyl-3,4,4a,5,6,7,10,11,12,12a-decahydrobenzocyclodecen-6-ol 
• 503071-63-4 (2S,3S)-1-{(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}-3-methoxymethoxypent-4-en-2-ol 
• 503071-64-5 (2R,3R)-1-{(1R,2R,6R)-2-[(2R)-2-(tert-butyl(diphenyl)silanyloxy)pent-4-enyl]-6-isopropyl-3-methylcyclohex-3-enyl}-3-methoxymethoxypent-4-en-2-ol 

Relevant academic research and scientific papers

Synthesis of a simplified sarcodictyin analogue which retains microtubule stabilising properties

A strategy featuring ring-closing metathesis as key reaction is applied to the synthesis of the sarcodictyin analogue 15. The precursor diene is accessed via a brief and efficient protocol, employing multiple stereoselective allylations. Simplified analog