402956-18-7Relevant academic research and scientific papers
P5X2+ (X = Br, I), a phosphorus-rich binary P-X cation with a C2v-symmetric P5 cage
Krossing,Raabe
, p. 4406 - 4409 (2001)
Insertion of the intermediately formed carbeneanaloguous PX2+ ion (X = Br, I) into one of the P-P bonds of the P4 tetrahedron led to the P5X2+ ion (see structure of the Br derivative)-the first example of the previously unknown class of phosphorus-rich binary P-X cations.
Reactions of P4 and I2 with Ag[Al(OC(CF3)3)4]: From elusive polyphosphorus cations to subvalent P3I6+ and phosphorus rich P5I2+
Krossing, Ingo
, p. 500 - 512 (2007/10/03)
Reactions of X2 (X = Br, I), P4 and Ag(CH2Cl2)[Al(OR)4] [R = C(CF3)3] in suitable ratios to prepare naked polyphosphorus cations were carried out and led to products which sugges
