403480-82-0

Basic information

• Product Name: 2,3,4,6-tetra-O-benzoyl-β-d-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-glucopyranosyl bromide
• Synonyms: 2,3,4,6-tetra-O-benzoyl-β-d-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-glucopyranosyl bromide
• CAS NO: 403480-82-0
• Molecular Weight: 1133.95
• Mol File: 403480-82-0.mol

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzoyl-β-d-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-glucopyranosyl bromide(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzoyl-β-d-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-glucopyranosyl bromide(403480-82-0)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzoyl-β-d-glucopyranosyl-(1→6)-2,3,4-tri-O-benzoyl-α-d-glucopyranosyl bromide(403480-82-0)

Safety Data

• Hazardous Substances Data: 403480-82-0(Hazardous Substances Data)

Upstream product

• 544686-94-4 1,2,3,4-tetra-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzoyl-β-D-glucopyranosyl)-α/β-D-glucopyranose 
• 536-11-8 gentibiose 
• 98-88-4 benzoyl chloride 

Downstream Products

• 165395-35-7 phenethyl-O-β-D-gluco-pyranosyl-(1′′→6′)-β-D-glucopyranoside 

Relevant articles and documents

Substrate specificity of beta-primeverosidase, a key enzyme in aroma formation during oolong tea and black tea manufacturing.

We synthesized nine kinds of diglycosides and a monoglycoside of 2-phenylethanol to investigate the substrate specificity of the purified beta-primeverosidase from fresh leaves of a tea cultivar (Camellia sinensis var. sinensis cv. Yabukita) in comparison with the apparent substrate specificity of the crude enzyme extract from tea leaves. The crude enzyme extract mainly showed beta-primeverosidase activity, although monoglycosidases activity was present to some extent. The purified beta-primeverosidase showed very narrow substrate specificity with respect to the glycon moiety, and especially prominent specificity for the beta-primeverosyl (6-O-beta-D-xylopyranosyl-beta-D-glucopyranosyl) moiety. The enzymes hydrolyzed naturally occurring diglycosides such as beta-primeveroside, beta-vicianoside, beta-acuminoside, beta-gentiobioside and 6-O-alpha-L-arabinofuranosyl-beta-D-glucopyranoside, but were unable to hydrolyze synthetic unnatural diglycosides. The purified enzyme was inactive toward 2-phenylethyl beta-D-glucopyranoside. The enzyme hydrolyzed each of the diglycosides into the corresponding disaccharide and 2-phenylethanol. These results indicate the beta-primeverosidase, a diglycosidase, to be a key enzyme involved in aroma formation during the tea manufacturing process.

Concise synthesis and antidiabetic activity of natural flavonoid glycosides, oroxins C and D, isolated from the seeds of Oroxylum indium

The first concise synthesis of natural flavonoid glycosides, oroxins C (1) and D (2), which were isolated from the seeds of Oroxylum indicum, was efficiently achieved by a convergent strategy. The synthesized natural products 1 and 2 were evaluated for th