403646-59-3

Upstream product

• 331456-83-8 S-phenyl 2,3-O-isopropylidene-4-O-(tert-butyldimethylsilyl)-1-thio-α-L-rhamnopyranoside 
• 403646-55-9 4-(4-nitrophenyl)butyl 4,6-O-benzylidene-2-O-pivaloyl-β-D-galactopyranoside 
• 403646-53-7 4-(4-nitrophenyl)butyl 4,6-O-benzylidene-3-O-(p-methoxybenzyl)-2-O-pivaloyl-β-D-galactopyranoside 
• 403646-42-4 S-phenyl 4,6-O-benzylidene-3-O-(p-methoxybenzyl)-2-O-pivaloyl-1-thio-β-D-galactopyranoside 
• 3282-30-2 pivaloyl chloride 
• 131087-35-9 phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 
• 1214-98-8 phenyl 1-thio-α-L-rhamnopyranose 

Downstream Products

• 403646-68-4 4-(4-nitrophenyl)butyl 4,6-O-benzylidene-2-O-pivaloyl-3-O-[4-O-(4,6-O-benzylidene-2,3-di-O-(p-methoxybenzyl)-β-D-mannopyranosyl)-2,3-O-isopropylidene-α-L-rhamnopyranosyl]-β-D-galactopyranoside 
• 403646-61-7 4-(4-nitrophenyl)butyl 4,6-O-benzylidene-2-O-pivaloyl-3-O-(2,3-O-isopropylidene-α-L-rhamnopyranosyl)-β-D-galactopyranoside 

Relevant academic research and scientific papers

Synthesis of the Salmonella type E(1) core trisaccharide as a probe for the generality of 1-(benzenesulfinyl)piperidine/triflic anhydride combination for glycosidic bond formation from thioglycosides.

A synthesis of a chromogenic glycoside of the Salmonella anatum group E(1) core trisaccharide is presented in which all three glycosidic bonds, a 1,2-cis-equatorial, a 1,2-trans-axial, and a 1,2-trans-equatorial linkage representing three of the four main classes of glycosidic bond, are formed with thioglycoside donors activated under a single set of conditions by the combination of 1-(benzenesulfinyl)piperidine and trifluoromethanesulfonic anhydride. 2,3-O-Carbonyl- and 2,3-O-isopropylidene-alpha-L-rhamnopyranosyl thioglycosides are found to be highly alpha-selective rhamnosyl donors under these conditions.