403666-51-3

Upstream product

• 994-30-9 triethylsilyl chloride 
• 209852-87-9 (-)-(1'S,2S)-2α-(1-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one 
• 875545-07-6 (S)-[1-Methoxy-1-(1-phenylethoxy)methylvinyloxy]triethylsilane 

Downstream Products

• 905984-03-4 (1S,2S,4S,5R)-2-fluoro-4-((S)-1-phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one 
• 905984-04-5 (1S,2S,4S,5R)-2-fluoro-4-acetoxy-8-oxabicyclo[3.2.1]oct-6-en-3-one 
• 403666-62-6 (1'S,1R,2S,3R,4R,5S)-(2-(1'-phenylethoxy)-3-(tert-butyldimethylsilanyloxy)-8-oxabicyclo[3.2.1]oct-6-en-4-yl) pivaloate 
• 403666-31-9 (1'S,1R,2R,3S,4S,5S)-(3-hydroxy-2-(1'-phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-4-yl) pivaloate 
• 403666-32-0 (1'S,1R,2R,3R,4S,5S)-(3-hydroxy-2-(1'-phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-4-yl) pivaloate 
• 403666-53-5 (1'S,1R,2S,4S,5S)-(2-(1'-phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one-4-yl) pivaloate 
• 403666-30-8 (1'S,1R,2S,4R,5S)-(2-(1'-phenylethoxy)-8-oxabicyclo[3.2.1]octa-6-ene-3-one-4-yl) pivaloate 
• 403666-52-4 (1'S,1R,2S,5S)-4-hydroxy-2-(1'-phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one 

Relevant academic research and scientific papers

Bicyclo[3.2.1]octanone catalysts for asymmetric alkene epoxidation: the effect of disubstitution

A series of 2-fluoro-8-oxabicyclo[3.2.1]octan-3-ones are prepared and tested as catalysts for alkene epoxidation with Oxone. These catalysts provide trans-stilbene oxide with up to 83% ee, but the highest ee value is obtained with the monofluorinated ketone 2: both 2,2- and 2,4-disubstituted catalysts afford epoxide of lower ee.

The Total Synthesis of C-Glycosides with Completely Resolved Seven-Carbon Backbone Polyol Stereochemistry: Stereochemical Correlations and Access to L-Configured and Other Rare Carbohydrates

The de novo synthesis of a full set of hydroxymethyl C-glycosides from only two precursors is described. The seven-carbon target molecules contain five stereocentres and bridge the stereochemical gap between natural D-configured and non-natural L-configur