403696-74-2

Upstream product

• 68-12-2 N,N-dimethyl-formamide 
• 403696-82-2 [(5Z)-7-(4-bromo-2,5-dimethoxy-phenyl)-6-methyl-hept-5-en-1-ynyl]-triisopropyl-silane 
• 403696-73-1 (5Z)-(6-iodo-hept-5-en-1-ynyl)-triisopropyl-silane 
• 87050-61-1 (4-bromo-2,5-dimethoxy-phenyl)-methanol 
• 120585-14-0 5-(tri-isopropylsilyl)pent-4-yn-1-ol 
• 2674-34-2 1,4-dibromo-2,5-dimethoxybenzene 
• 31558-41-5 4-bromo-2,5-dimethoxybenzaldehyde 
• 13154-24-0 triisopropylsilyl chloride 
• 5390-04-5 pent-1-yn-5-ol 
• 403696-81-1 5-(triisopropylsilyl)-4-pentyn-1-al 

Downstream Products

• 403696-83-3 2-Hydroxy-5-methoxy-4-((Z)-2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-benzaldehyde 
• 403696-88-8 1-[2-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-4-(2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-phenyl]-3-(tert-butyl-dimethyl-silanyloxymethyl)-hexa-2,5-dien-1-ol 
• 403696-80-0 1-(tert-butyl-dimethyl-silanyloxy)-2-[1-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-hexa-2,5-dienyl]-4-methoxy-5-(2-methyl-hept-2-en-6-ynyl)-benzene 
• 403696-84-4 (E)-(S)-1-[2-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-((Z)-2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-phenyl]-3-methyl-6-trimethylsilanyl-hex-2-en-5-yn-1-ol 
• 403696-77-5 1-(tert-butyl-dimethyl-silanyloxy)-2-[1-(tert-butyl-dimethyl-silanyloxy)-3-methyl-hexa-2,5-dienyl]-4-methoxy-5-(2-methyl-hept-2-en-6-ynyl)-benzene 
• 403696-85-5 2-((E)-(S)-1-Hydroxy-3-methyl-hex-2-en-5-ynyl)-4-methoxy-5-((Z)-2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-phenol 
• 403696-86-6 2-((E)-(S)-1-Hydroxy-3-methyl-hexa-2,5-dienyl)-4-methoxy-5-((Z)-2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-phenol 
• 403696-75-3 2-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-4-(2-methyl-7-triisopropylsilanyl-hept-2-en-6-ynyl)-benzaldehyde 
• 403696-79-7 (E)-(S)-3-Allyl-1-[2-hydroxy-5-methoxy-4-((Z)-2-methyl-hept-2-en-6-ynyl)-phenyl]-but-2-ene-1,4-diol 
• 403696-87-7 2-((E)-(S)-1-Hydroxy-3-methyl-hexa-2,5-dienyl)-4-methoxy-5-((Z)-2-methyl-hept-2-en-6-ynyl)-phenol 

Relevant academic research and scientific papers

Biomimetic synthesis of (-)-longithorone A

An enantioseletive, biomimetic synthesis of (-)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer control during ene-yne metathesis macrocyclizations. Copyright