403696-75-3Relevant academic research and scientific papers
Biomimetic synthesis of (-)-longithorone A
Layton, Mark E.,Morales, Carl A.,Shair, Matthew D.
, p. 773 - 775 (2007/10/03)
An enantioseletive, biomimetic synthesis of (-)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer control during ene-yne metathesis macrocyclizations. Copyright
