403790-46-5Relevant academic research and scientific papers
On the steric acceleration of ene reactions
Choony, Nandeo,Kuhnert, Nikolai,Sammes, Peter G.,Smith, Graham,Ward, Robert W.
, p. 1999 - 2005 (2007/10/03)
Steric buttressing, using the removable trityl group as a protecting group for substituted allylamines, is used to effect selective cycloadditions and uncatalysed ene reactions under remarkably mild conditions.
Steric acceleration of an uncatalysed ene reaction at room temperature
Choony,Sammes,Smith,Ward
, p. 2062 - 2063 (2007/10/03)
The bulky trityl steric buttress is used to effect an intramolecular, uncatalysed ene reaction that operates at room temperature, whilst smaller buttresses require heat.
