403790-45-4Relevant academic research and scientific papers
Steric acceleration of an uncatalysed ene reaction at room temperature
Choony,Sammes,Smith,Ward
, p. 2062 - 2063 (2001)
The bulky trityl steric buttress is used to effect an intramolecular, uncatalysed ene reaction that operates at room temperature, whilst smaller buttresses require heat.
On the steric acceleration of ene reactions
Choony, Nandeo,Kuhnert, Nikolai,Sammes, Peter G.,Smith, Graham,Ward, Robert W.
, p. 1999 - 2005 (2007/10/03)
Steric buttressing, using the removable trityl group as a protecting group for substituted allylamines, is used to effect selective cycloadditions and uncatalysed ene reactions under remarkably mild conditions.
