404-19-3Relevant academic research and scientific papers
Synthesis and Diels-Alder cycloaddition reactions of [(2,2-dichloro-1- fluoroethenyl)sulfinyl] benzene and [(2-chloro-1,2-difluoro ethenyl)sulfinyl] benzene
Sridhar, Madabhushi,Leela Krishna,Madhusudana Rao, Jampani
, p. 3539 - 3545 (2007/10/03)
Synthesis of [(2,2-dichloro-1-fluoroethenyl)sulfinyl] benzene and [(2- chloro-1,2-difluoro ethenyl)sulfinyl] benzene and their Dieis-Alder cycloadditions with cyclopentadiene, furan and 1,3-diphenylisobenzofuran under thermal and microwave irradiation conditions are described. 2000 Elsevier Science Ltd.
Microwave activated Diels-Alder Cycloaddition reactions of 1,2-difluoro- 1-chlorovinylphenylsulfone
Sridhar, Madabhushi,Krishna, K. Leela,Srinivas,Rao, Jampani Madhusudana
, p. 6529 - 6532 (2007/10/03)
Diels-Alder Cycloadditions of 1,2-difluoro-1-chlorovinylphenylsulfone with cyclopentadiene, furan and 1,3-diphenylisobenzofuran are studied under thermal and microwave activation conditions. Microwave heating is found to be more efficient method for condensation of fluorinated dienophile with dienes.
Synthesis and dienophilic reactivity of 1,2-difluorovinylphenylsulfone
De Tollenaere,Ghosez
, p. 17127 - 17138 (2007/10/03)
1,2-Difluorovinylphenylsulfone 5 was conveniently prepared in three steps from chlorotrifluoroethylene. Both E and Z isomers of 5 gave excellent yields of [4+2] cycloadducts with cyclopentadiene. The E isomer reacted with high kinetic exo selectivity. 1,2
