404392-85-4

Upstream product

• 93-98-1 N-phenyl benzoyl amide 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 404392-73-0 C₂₉H₂₉NOSi 
• 774-40-3 hydroxy-phenyl-acetic acid ethyl ester 

Downstream Products

• 306961-67-1 benzyl-[2-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-ethylidene]-amine 
• 306961-33-1 (tert-butyl-diphenyl-silanyloxy)-phenyl-acetaldehyde 

Relevant academic research and scientific papers

Si-BEZA - Catalytic pyridinium triflate: A mild and powerful agent for the silylation of alcohols

A highly efficient method of silylation using a novel agent, Si-BEZA (silylbenzamide), together with a pyridinium triflate catalyst was developed, wherein a variety of silyl groups can be introduced into sterically crowded alcohols under mild conditions.

Comparative Study of the Diastereoselective Addition of Allenyl Zinc Reagents to α-Alkoxy (or Silyloxy) Aldehydes and Imines. A Straightforward Synthesis of Amino Alcohols from Imines

The addition of allenylzinc bromides to α-chiral imines proceeds with very high diastereoselectivity. This result is in contrast with the addition to the corresponding aldehydes, leading to poor diastereoselectivity. The anti/anti adducts are explained by Felkin-Ahn and Gaudemar-Yamamoto models of the transition state.