4045-72-1Relevant academic research and scientific papers
METHODS FOR PRODUCTION OF 1,2,4-TRIAZOL-3-ONE
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Page/Page column 4-5, (2009/04/25)
Novel methods for producing 1,2,4-triazol-3-one from semicarbazide hydrochloride and formic acid are provided. In methods of this invention, water is used in removal of unreacted formic acid to increase yield and purity of produced 1,2,4-triazol-3-one.
METHODS FOR PRODUCTION OF 1,2,4-TRIAZOL-3-ONE
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Page/Page column 3-4, (2009/04/25)
Novel methods for producing 1,2,4-triazoI-3-one from semicarbazide hydrochloride and formic acid are provided. In methods of this invention, ethanol is used in removal of unreacted formic acid to increase yield and purity of produced 1,2,4-triazol-3-one.
Process for low chloride 1,2,4-triazol-5-one
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, (2008/06/13)
A process for producing 1,2,4-triazol-5-one comprises reacting a semicarbazide compound with a formic acid compound formylating agent in the presence of a catalytic amount of a sulfur-oxygen containing acid. The process is able to produce 1,2,4-triazol-5-one from semicarbazide hydrochloride having significantly lower concentrations of chloride ion, which is advantageous, for example, in the production of 3-nitro-1,2,4-triazol-5-one as an explosive used in castable explosive compositions.
Process for low chloride 1,2,4-triazol-5-one
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, (2008/06/13)
A process for producing 1,2,4-triazol-5-one reacts an aqueous hydrazine solution with urea to form a reaction mixture of semicarbazide and ammonia, the reaction mixture is concentrated and an aqueous solution of a mineral acid added to form a slurry of a salt of semicarbazide. A formic acid compound is admixed with the slurry, and the slurry heated to produce 1,2,4-triazol-5-one. The novel process results in the production of a semicarbazide salt in situ and eliminates a number of process steps required in processes of the prior art.
