40463-26-1Relevant academic research and scientific papers
Addition of Organozinc Compounds to C=C-Bonds, III. --- Addition of Bis(2-methylallyl)zinc to para- and meta- Substituted Styrenes
Lehmkuhl, Herbert,McLane, Raymond
, p. 736 - 743 (2007/10/02)
A Hammett correlation between the ratio of M --> Cprim/M --> Csec addition and the substituent constants ?+ has been found for the addition of bis(2-methylallyl)zinc (1) to p- and m-substituted styrenes 2-8.Electron donating substituents favour M --> Cprim addition, electron withdrawing substituents M --> Csec addition.
