626-20-0

Basic information

• Product Name: 3-VINYLANISOLE 97
• Synonyms: 3-VINYLANISOLE 97;3-Methoxystyrene, (Stabilized with 4-t-Butylcatechol);1-Ethenyl-3-methoxybenzene;1-Vinyl-3-methoxybenzene;m-Methoxystyrene;3-Vinylanisole 97%;1-Methoxy-3-vinylbenzene
• CAS NO: 626-20-0
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.18
• Product Categories: Acyclic;Alkenes;Organic Building Blocks
• Mol File: 626-20-0.mol
• Article Data: 71

Chemical Properties

• Boiling Point: 204-205 °C(lit.)
• Flash Point: 172 °F
• Appearance: /
• Density: 0.967 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.5540(lit.)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 3-VINYLANISOLE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 3-VINYLANISOLE 97(626-20-0)
• EPA Substance Registry System: 3-VINYLANISOLE 97(626-20-0)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 626-20-0(Hazardous Substances Data)

Usage

General Description

Inhibited with 1000ppm p-tert-butylcatechol

Upstream product

• 2845-89-8 1-chloro-3-methoxy-benzene 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 67-56-1 methanol 
• 5020-41-7 2-(3-methoxyphenyl)-ethanol 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 591-31-1 3-methoxy-benzaldehyde 
• 179248-84-1 1-(3-methoxyphenyl)prop-2-yn-1-ol 
• 65-85-0 benzoic acid 
• 74-85-1 ethene 
• 766-85-8 3-methoxy-1-iodobenzene 
• 21550-06-1 1-(3-methoxyphenyl)butan-1-one 
• 32017-77-9 2-(m-methoxyphenyl)oxirane 
• 2398-37-0 3-methoxyphenyl bromide 
• 56578-36-0 3-methoxycinnamaldehyde 

Downstream Products

• 10568-38-4 3-ethylanisole 
• 37728-89-5 1-(1,2-dibromoethyl)-3-methoxybenzene 
• 93521-56-3 2-[2-(3-Methoxy-phenyl)-aziridin-1-yl]-isoindole-1,3-dione 
• 71778-34-2 (1R*,2R*)-ethyl 2-(3-methoxyphenyl)cyclopropanecarboxylate 
• 82414-97-9 C₉H₁₁O⁽¹⁺⁾ 
• 119087-31-9 2-{3-[2-(3-Methoxy-phenyl)-cyclopropyl]-3-oxo-propyl}-2-methyl-cyclopentane-1,3-dione 
• 96728-33-5 trans-1-(m-methoxyphenyl)-2-<β-(2-methyl-1,3-dioxocyclopent-2-yl)propionyl>cyclopropane 

Relevant articles and documents

Functionalized styrene synthesis via palladium-catalyzed C[sbnd]C cleavage of aryl ketones

We report herein the synthesis of functionalized styrenes via palladium-catalyzed Suzuki–Miyaura cross-coupling reaction between aryl ketone derivatives and potassium vinyltrifluoroborate. The employment of pyridine-oxazoline ligand was the key to the cleavage of unstrained C[sbnd]C bond. A variety of functional groups and biologically important moleculars were well tolerated. The orthogonal Suzuki–Miyaura coupling demonstrated the synthetic practicability.

Nickel-Catalyzed Enantioselective Hydroboration of Vinylarenes

The enantioselective hydroboration of vinylarenes catalyzed by a chiral, nonracemic nickel catalyst is presented as a facile method for generating chiral benzylic boronate esters. Various vinylarenes react with bis(pinacolato)diboron (B2pin2) in the presence of MeOH as a hydride source to form chiral boronate esters in up to 92% yield with up to 94% ee. The use of anhydrous Me4NF to activate B2pin2 is crucial for ensuring fast transmetalation to achieve high enantioselectivities.

COMPOUNDS AND USES THEREOF

The present disclosure features compounds useful for the treatment of BAF complex-related disorders.