40486-55-3Relevant articles and documents
A CONVENIENT AND STEREOSELECTIVE SYNTHESIS OF ALLYLIC SULFIDES
Harano, Kazunobu,Ohizumi, Norihide,Hisano, Takuzo
, p. 4203 - 4206 (2007/10/02)
The fractional distillation of O-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates (xanthates) affords 2-alkenyl or 2-cycloalkenyl alkyl sulfides.The reaction involves the -sigmatropic rearrangement of the xanthates to produce S-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates followed by extrusion of carbon oxysulfide to give 2-alkenyl or 2-cycloalkenyl alkyl sulfides.