405897-29-2Relevant academic research and scientific papers
Reaction of Propargyl Bromide with Aldehydes in the Presence of Metallic Tin. Synthesis of Homopropargylalcohols and Homoallenylalcohols
Wu, Shihui,Huang, Bangzhou,Gao, Xiang
, p. 1279 - 1286 (2007/10/02)
In the presence of water, metallic tin and propargyl bromide reacted smoothly with aldehydes to give the corresponding homopropargyl alcohols (a) and homoallenyl alcohols (b).High chemospecifity to bifunctional carbonyl compounds containing -OH, -X and -NO2 etc. was obtained.
The Synthesis of a Cyclopropane Amino Acid, trans-α-(Carboxycyclopropyl)glycine, found in Ackee Seed
Landor, Stephen R.,Landor, Phyllis, D.,Kalli, Michael
, p. 2921 - 2926 (2007/10/02)
trans-α-(Carboxycyclopropyl)glycine, a constituent of ackee seed (Blighia sapida), has been synthesized via the key intermediate ethyl (E)-4,4-diethoxybut-2-enoate.
