40596-08-5Relevant academic research and scientific papers
Diastereoselective addition of γ-substituted allylic nucleophiles to ketones: Highly stereoselective synthesis of tertiary homoallylic alcohols using an allylic tributylstannane/stannous chloride system
Yasuda, Makoto,Hirata, Kay,Nishino, Mitsuyoshi,Yamamoto, Akihiro,Baba, Akio
, p. 13442 - 13447 (2002)
The diastereoselective addition of γ-substituted allylic nucleophiles to ketones has been accomplished to give tertiary homoallylic alcohols. The reaction of tributylcinnamyltin 1a with simple ketones 2 in the presence of stannous chloride (SnCl2/su
