40596-18-7Relevant academic research and scientific papers
Reversible stereocontrol in the Lewis acid promoted reaction of alkoxyaldehydes toward various allyltins
Nishigaichi, Yutaka,Takuwa, Akio
, p. 1405 - 1408 (2003)
In the reactions of variously substituted allyltin reagents toward achiral alkoxyaldehydes, one of the diastereomeric homoallyl alcohols was stereoselectively obtained by the help of BF3, while TiCl4 preferentially gave the other dia
Reaction of allylic-type diindium compounds with electrophiles
Hirashita, Tsunehisa,Arai, Shun,Mitsui, Kazuma,Makino, Hajime,Araki, Shuki
, p. 314 - 315 (2007/10/03)
Allylic-type diindium reagents were prepared from 3-bromo-1-iodopropene (1a), 3-bromo-1-iodo-1-phenylpropene (1b), or 2,4-diiodobut-2-en-1-ol (1c) with metallic indium, and their successive coupling with electrophiles was examined. The coupling behavior o
Synthesis of Enantiomerically Enriched anti-Homoallyl Alcohols Mediated by Crude Chicken Liver Esterase (CCLE)
Basavaiah, Deevi,Dharma Rao, Polisetti
, p. 789 - 800 (2007/10/02)
Enantiomerically enriched anti-homoallyl alcohols were synthesized in 6799percent enantiomeric purities via enantioselective hydrolysis of the corresponding racemic acetates mediated by Crude Chicken Liver Esterase (CCLE).
On the Transmetallation of (E)-1-Phenyl-3-(tributylstannyl)propene and 3-Phenyl-3-(tributylstannyl)propene with BuSnCl3
Miyake, Hideyoshi,Yamamura, Kimiaki
, p. 1473 - 1474 (2007/10/02)
Transmetallation of (E)-1-phenyl-3-(tributylstannyl)propene and 3-phenyl-3-(tributylstannyl)propene with BuSnCl3, and the isomerization of the transmetallated product are described.The application of the reactions to stereoselective (Z)-3-phenyl-2-propenylation and threo-1-phenyl-2-propenylation of aldehydes is also described.
DIASTEREOSELECTIVITY, DIASTEREOFACIAL SELECTIVITY AND REGIOSELECTIVITY IN THE REACTIONS OF CYNNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM
Coxon, James M.,Eyk, Stephen J. van,Steel, Peter J.
, p. 1029 - 1042 (2007/10/02)
The reaction of cinnamyl chlorie with a series of aryl and alkyl aldehydes mediated by tin and aluminium has been shown to be regioselective and threo diastereoselective.For aldehydes with chirality adjacent to the carbonyl function some diastereofacial s
REDUCTIVE GENERATION OF ACTIVE ZERO-VALENT TIN IN SnCl2-Al SYSTEM AND ITS USE FOR HIGHLY DIASTEREOSELECTIVE REACTION OF CINNAMYL CHLORIDE AND ALDEHYDES.
Uneyama, Kenji,Nanbu, Hiromi,Torii, Sigeru
, p. 2395 - 2396 (2007/10/02)
Highly diastereoselective reaction of cinnamyl chloride with aldehydes was achieved by the use of active zero-valent tin generated in SnCl2-Al system.
HIGHLY DIASTEREOSELECTIVE REACTIONS OF (E)-CINNAMYL CHLORIDE WITH ALDEHYDES MEDIATED BY TIN AND ALUMINIUM
Coxon, James M.,Eyk, Stephen J. van,Steel, Peter J.
, p. 6121 - 6124 (2007/10/02)
The reactions of (E)-cinnamyl chloride with aldehydes in H2O:THF:HBr in the presence of tin and aluminium powders proceed with very high stereoselectivity.
