406179-88-2

Basic information

• Product Name: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole
• Synonyms: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole
• CAS NO: 406179-88-2
• Molecular Weight: 249.334
• Mol File: 406179-88-2.mol

Chemical Properties

• CAS DataBase Reference: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(406179-88-2)
• EPA Substance Registry System: 1-(p-toluenesulfonyl)-5-vinyl-2,3-dihydro-1H-pyrrole(406179-88-2)

Safety Data

• Hazardous Substances Data: 406179-88-2(Hazardous Substances Data)

Upstream product

• 205885-42-3 N-(but-3-en-1-yl)-N-ethynyl-4-methylbenzenesulfonamide 
• 888488-24-2 (Z)-N-ethynyl-N-(hex-3-enyl)-p-toluenesulfonamide 
• 406179-98-4 N-(but-3-enyl)-N-(2,2-dichlorovinyl)-p-toluenesulfonamide 
• 888488-16-2 (Z)-N-formyl-N-(hex-3-enyl)-p-toluenesulfonamide 
• 888488-20-8 (Z)-N-(2,2-dichlorovinyl)-N-(hex-3-enyl)-p-toluenesulfonamide 
• 4917-56-0 N-formyl-N-tosylamide 
• 10285-80-0 N-tosyl-3-butenylamine 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 
• 126745-58-2 1,1-dimethylethyl (Z)-3-hexenyl[(4-methylphenyl)sulfonyl]carbamate 
• 177972-59-7 N-[(3Z)-hex-3-en-1-yl](4-methylphenyl)sulfonamide 
• 208335-94-8 N-(but-3-en-1-yl)-N-(tert-butoxycarbonyl)-4-methylbenzenesulfonamide 
• 853688-07-0 C₁₂H₁₅NO₃S 

Relevant articles and documents

Diastereoselective gold-catalyzed cycloisomerizations of Ene-ynamides

(Chemical Equation Presented) Around they go: 1,6-Ene-ynamides undergo highly diastereoselective gold-catalyzed cycloisomerizations that lead to functionalized cyclobutanones or carbonyl compounds with a 2-azabicyclo-[3.1.0] hexane subunit, depending on t

Synthesis of different ring-size heterocycles from the same propargyl alcohol derivative by ligand effect on Pd(0)

The type of ligand on an allenylpalladium complex, which was prepared from propargyl alcohol derivative and Pd(0), plays an important role in determination of the ring size of the cyclized compound. An intermediary palladium complex bearing a monodentate ligand gave a cyclized compound via palladacycle, while that bearing a bidentate ligand gave one-carbon elongated cyclized compound via a η3-propargylpalladium complex.

Radical cascade cyclizations and platinum(II)-catalyzed cycloisomerizations of ynamides

Ynamides are tested as new partners in radical and organometallic transformations. A radical cascade involving a 5-exo-dig cyclization followed by a 6-endo-trig radical trapping transforms ynamides into hetero-polycyclic compounds such as isoindoles, isoindolinones and pyrido-isoindolones. Various ene-tosylynamides react with platinum(II) chloride and lead to bicyclic nitrogenated heterocycles. This unprecedented and easily operated process can be coupled with a hydrolysis of the intermediate cyclic tosylenamides in a one-pot transformation, which provides cyclobutanones.

Synthesis of cyclic dienamide using ruthenium-catalyzed ring-closing metathesis of ene-ynamide

Ring-closing metathesis of ene-ynamide, which has alkene and ynamide moieties in a molecule, using a second-generation ruthenium carbene complex produced nitrogen-containing heterocycles, which have a dienamide moiety, in high yields. Diels-Alder reaction

Platinum dichloride-catalyzed cycloisomerization of ene-ynamides

Various ene-tosylynamides react with platinum(II) chloride and lead to bicyclic nitrogenated heterocycles. This unprecedented and easily operated process can be coupled with a hydrolysis of the intermediate cyclic tosylenamides in a one-pot transformation

Synthesis of cyclic dienamide using ruthenium-catalyzed ring-closing metathesis of ene-ynamide.

[reaction: see text] Ring-closing metathesis of ene-ynamide using the second-generation Grubbs' catalyst produced nitrogen-containing heterocycles, which have dienamide moieties, in high yields. Diels-Alder reaction of the cyclized product and dienophile