406218-90-4Relevant academic research and scientific papers
Asymmetric synthesis of 1-aryl-1,2-ethanediols from arylacetylenes by palladium-catalyzed asymmetric hydrosilylation as a key step
Shimada, Toyoshi,Mukaide, Kotaro,Shinohara, Akihiro,Han, Jin Wook,Hayashi, Tamio
, p. 1584 - 1585 (2002)
Double hydrosilylation of arylacetylenes with trichlorosilane catalyzed first by platinum and second by a chiral monophosphine-palladium complex generated the corresponding 1,2-bis(silyl)-1-arylethanes, the oxidation of which with hydrogen peroxide gave 1-aryl-1,2-diols of high enantiomeric purity (94-98% ee) in high yields. Copyright
Direct synthesis of porous organosilicas containing chiral organic groups within their framework and a new analytical method for enantiomeric purity of organosilicas
Inagaki, Shinji,Guan, Shiyou,Yang, Qihua,Kapoor, Mahendra P.,Shimada, Toyoshi
, p. 202 - 204 (2008)
Organosilica porous solids containing chiral organic moieties in the framework with an enantiomeric purity of 95% ee, estimated by eluting organic constituent units from chiral organosilicas, were synthesized from a newly designed chiral (R)-(+)-1,2-bis(t
