406725-90-4Relevant academic research and scientific papers
Synthesis of novel α-substituted and α,α-disubstituted amino acids by rearrangement of ammonium ylides generated from metal carbenoids
Clark, J. Stephen,Middleton, Mark D.
, p. 765 - 768 (2007/10/03)
(equation presented) A new and general four-step synthesis of protected a-substituted and α,α-disubstituted amino acids has been developed. The key step involves intramolecular ammonium ylide generation from a copper carbenoid with concomitant [2,3] rearr
