4071-74-3

Basic information

• Product Name: Cyclohexanone, 2,6-dimethyl-2-(3-oxobutyl)-
• CAS NO: 4071-74-3
• Molecular Formula: C12H20O2
• Molecular Weight: 196.29
• Mol File: 4071-74-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2,6-dimethyl-2-(3-oxobutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2,6-dimethyl-2-(3-oxobutyl)-(4071-74-3)
• EPA Substance Registry System: Cyclohexanone, 2,6-dimethyl-2-(3-oxobutyl)-(4071-74-3)

Safety Data

• Hazardous Substances Data: 4071-74-3(Hazardous Substances Data)

Usage

General Description

Cyclohexanone, 2,6-dimethyl-2-(3-oxobutyl)- is a chemical compound with the molecular formula C14H24O2. It is a cyclic ketone with a six-membered ring structure and two methyl groups at the 2 and 6 positions, as well as a 3-oxobutyl substituent. This chemical is commonly used as a solvent and intermediate in the production of various products, including nylon and pharmaceuticals. It may also be used as a reagent in organic synthesis and as a flavoring agent in the food industry. Its unique structure and properties make it a versatile and valuable compound in various industrial and commercial applications.

Upstream product

• 2816-57-1 2,6-dimethylcyclohexanone 
• 78-94-4 methyl vinyl ketone 
• 63547-53-5 2,6-dimethyl-1-(trimethylsiloxy)cyclohexene 
• 13652-48-7 N-isopropyl-N-(2,6-dimethylcyclohexylidene)amine 
• 67935-23-3 trans-3-methoxybut-2-en-1-ol 

Downstream Products

• 4071-63-0 rac-4a,8-dimethyl-3,4,4a,5,6,7,8-heptahydronaphthalen-2-one 
• 256487-36-2 2,6-Dimethyl-2-[2-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-ethyl]-cyclohexanone 
• 256487-37-3 2-[2-(1,3-Dimethyl-2-methylene-cyclohexyl)-ethyl]-2,5,5-trimethyl-[1,3]dioxane 

Relevant articles and documents

Lipase-catalyzed Asymmetric Synthesis of Enantiomerically Pure (2S,4aS,8S)-4a,8-Dimethyl-2,3,4,4a,5,6,7,8-octahydro-2-naphthalenol

Enantiomerically pure (2S,4aS,8S)-(+)-4a,8-dimethyl-2,3,4,4a,5,6,7,8-octahydro-2-naphthalenol (3), a key intermediate in the synthesis of natural geosmin (1), was prepared by enzymatic kinetic resolution. When racemic 3 was submitted to lipase (PS-30)-cataIyzed asymmetric acetylation, employing vinyl acetate as the acyl donor, requisite product (+)-3 with a high enantiomeric excess was attained as the remaining alcohol. Recrystallization resulted in an enantiomerically pure sample. - Keywords: lipase; kinetic resolution; asymmetric acetylation; geosmin; musty odour component.

Organotin Triflate as Practical Catalyst for Michael Addition of Enol Silyl Ethers

Dibutyltin bis(triflate) is a mild Lewis acid which catalyzes clean Michael addition of enol silyl ethers.The new catalyst allows to employ various labile acceptors such as methyl vinyl ketone and 2-cyclopentenone which do not undergo smooth reaction with

8,16- And 8,18-methanobacteriorhodopsin. Synthesis and spectroscopy of 8,16- and 8,18-methanoretinal and their interaction with bacterioopsin

8,16- And 8,18-methanoretinal with a locked 6-s-trans and a 6-s-cis conformation have been synthesized and characterized.Their 9-Z and 13-Z isomers could also be prepared, in contrast to the 11-Z. 8,16-Methanoretinal easily binds with bacterioopsin (bO) to form a bacteriorhodopsin analogue which closely resembles natural bacteriorhodopsin (bR) (λmax, light-dark adaptation and proton pump action).The interaction of 8,18-methanoretinal with bO is complex.These findings give additional support to the fact that in bR the chromophore occurs in the planar 6-s-trans conformation.Approximately 1200 cm-1 of the opsin shift in bR (5100 cm-1) arises because the chromophore changes upon binding to the protein from a 40 deg twisted 6-s-cis to a planar 6-s-trans conformation.Both 8,16- and 8,18-methano bR have a ca. 3900 cm-1 opsin shift, since the C6-C7 conformation does not allow protein-induced changes.This is consistent with the idea that the opsin shift is mainly due to the perturbation of the Schiff base region.