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2-Aminomethylphenylacetic acid
Cas No: 40851-65-8
No Data No Data No Data Chemsigma International Co.,Ltd. Contact Supplier
2-Aminomethylphenylacetic acid
Cas No: 40851-65-8
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality 2-Aminomethylphenylacetic Acid supplier in China
Cas No: 40851-65-8
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
2-[2-(ammoniomethyl)phenyl]acetate
Cas No: 40851-65-8
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
2-Aminomethylphenylacetic acid 40851-65-8
Cas No: 40851-65-8
USD $ 500.0-500.0 / Metric Ton 1 Metric Ton 1 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier
Pharmaceutical Grade CAS 40851-65-8 with competitive price
Cas No: 40851-65-8
USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
BLOOM TECH Advanced API/Technology support 2-Aminomethylphenylacetic acid CAS 40851-65-8
Cas No: 40851-65-8
No Data 1 Gram 3 Metric Ton/Month Shaanxi BLOOM TECH Co.,Ltd Contact Supplier
Benzeneacetic acid,2-(αminomethyl)- 40851-65-8
Cas No: 40851-65-8
No Data 1 Kilogram 10000 Metric Ton/Month Shanghai Upbio Tech Co.,Ltd Contact Supplier
2-Aminomethylphenylacetic acid
Cas No: 40851-65-8
No Data 1 Kilogram 1 Metric Ton/Day Shandong Hanjiang Chemical Co., Ltd. Contact Supplier
2-Aminomethylphenylacetic Acid
Cas No: 40851-65-8
No Data No Data No Data Xiamen Hisunny Chemical Co.,Ltd Contact Supplier

40851-65-8 Usage

InChI:InChI=1/C9H11NO2.ClH/c10-6-8-4-2-1-3-7(8)5-9(11)12;/h1-4H,5-6,10H2,(H,11,12);1H

40851-65-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name [2-(Aminomethyl)phenyl]acetic Acid

1.2 Other means of identification

Product number -
Other names 2-Aminomethylphenylacetic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:40851-65-8 SDS

40851-65-8Synthetic route

sodium 2-(1-ethoxycarbonyl-1-propen-2-ylaminomethyl)phenylacetate
52786-77-3

sodium 2-(1-ethoxycarbonyl-1-propen-2-ylaminomethyl)phenylacetate

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
With hydrogenchloride In water pH=2; Cooling with ice;79%
2-(tert-butoxycarbonylaminomethyl)phenylacetic acid
40851-66-9

2-(tert-butoxycarbonylaminomethyl)phenylacetic acid

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
With trifluoroacetic acid In diethyl ether at 20℃;78%
[2-(benzoylamino-methyl)-phenyl]-acetonitrile
170306-38-4

[2-(benzoylamino-methyl)-phenyl]-acetonitrile

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
With hydrogenchloride at 115℃; im Rohr;
2-(2-(azidomethyl)phenyl)acetic acid
40851-64-7

2-(2-(azidomethyl)phenyl)acetic acid

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal
o-chloromethylbenzylamine
38379-25-8

o-chloromethylbenzylamine

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: NaOH-solution / unter Kuehlung
2: diluted alcohol
3: concentrated hydrochloric acid / 115 °C / im Rohr
View Scheme
N-(2-chloromethyl-benzyl)-benzamide
28837-90-3

N-(2-chloromethyl-benzyl)-benzamide

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: diluted alcohol
2: concentrated hydrochloric acid / 115 °C / im Rohr
View Scheme
bis-(2-ethoxymethyl-benzyl)-amine
861338-62-7

bis-(2-ethoxymethyl-benzyl)-amine

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: alcohol; hydrogen chloride
2: NaOH-solution / unter Kuehlung
3: diluted alcohol
4: concentrated hydrochloric acid / 115 °C / im Rohr
View Scheme
Multi-step reaction with 4 steps
2: NaOH-solution / unter Kuehlung
3: diluted alcohol
4: concentrated hydrochloric acid / 115 °C / im Rohr
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

2-[2-(aminomethyl)cyclohexyl]acetic acid

2-[2-(aminomethyl)cyclohexyl]acetic acid

Conditions
ConditionsYield
With 5wt.% Rh on activated alumina; hydrogen In water at 100℃; under 13501.4 Torr; for 24h; Autoclave;92%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

2-(tert-butoxycarbonylaminomethyl)phenylacetic acid
40851-66-9

2-(tert-butoxycarbonylaminomethyl)phenylacetic acid

Conditions
ConditionsYield
With water In 1,4-dioxane at 0 - 20℃; for 3.16667h;88.1%
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

ethyl acetoacetate
141-97-9

ethyl acetoacetate

sodium 2-(1-ethoxycarbonyl-1-propen-2-ylaminomethyl)phenylacetate
52786-77-3

sodium 2-(1-ethoxycarbonyl-1-propen-2-ylaminomethyl)phenylacetate

Conditions
ConditionsYield
With sodium In ethanol Reflux;82.3%
(fluorenylmethoxy)carbonyl chloride
28920-43-6

(fluorenylmethoxy)carbonyl chloride

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

2-(2-(((((9H-fluoren-9-yl)methoxy)carbonyl)amino)methyl)phenyl)acetic acid

2-(2-(((((9H-fluoren-9-yl)methoxy)carbonyl)amino)methyl)phenyl)acetic acid

Conditions
ConditionsYield
With potassium carbonate In 1,4-dioxane; water at 20℃; for 2h;25%
Yield given;
With sodium carbonate In 1,4-dioxane; water at 20℃;
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

2-(4-((1H-pyrazol-1-yl)methyl)benzyl)-4-chloro-2H-pyrazolo[3,4-d]pyrimidine

2-(4-((1H-pyrazol-1-yl)methyl)benzyl)-4-chloro-2H-pyrazolo[3,4-d]pyrimidine

2-(2-((2-(4-((1H-pyrazol-1-yl)methyl)benzyl)-2H-pyrazolo[3,4-d]pyrimidin-4-ylamino)methyl)phenyl)acetic acid

2-(2-((2-(4-((1H-pyrazol-1-yl)methyl)benzyl)-2H-pyrazolo[3,4-d]pyrimidin-4-ylamino)methyl)phenyl)acetic acid

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 60℃;2%
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

1,4-dihydro-3(2H)-isoquinolinone
24331-94-0

1,4-dihydro-3(2H)-isoquinolinone

Conditions
ConditionsYield
unter vermindertem Druck;
Multi-step reaction with 2 steps
1: aqueous alkaline solution
2: soda lime / 200 - 250 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

acetic anhydride
108-24-7

acetic anhydride

[2-(acetylamino-methyl)-phenyl]-acetic acid
112072-92-1

[2-(acetylamino-methyl)-phenyl]-acetic acid

Conditions
ConditionsYield
With alkaline solution
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

butyryl chloride
141-75-3

butyryl chloride

[2-(butyrylamino-methyl)-phenyl]-acetic acid
100609-65-2

[2-(butyrylamino-methyl)-phenyl]-acetic acid

Conditions
ConditionsYield
With alkaline solution
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(S)-1-((R)-3-tert-Butoxycarbonylamino-4-phenyl-butyryl)-pyrrolidine-2-carboxylic acid
775354-22-8

(S)-1-((R)-3-tert-Butoxycarbonylamino-4-phenyl-butyryl)-pyrrolidine-2-carboxylic acid

[2-({[(S)-1-((R)-3-tert-Butoxycarbonylamino-4-phenyl-butyryl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid

[2-({[(S)-1-((R)-3-tert-Butoxycarbonylamino-4-phenyl-butyryl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid

Conditions
ConditionsYield
With benzotriazol-1-ol; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; N-ethyl-N,N-diisopropylamine In dichloromethane
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(S)-1-((S)-2-tert-Butoxycarbonylamino-2-cyclohexyl-acetyl)-pyrrolidine-2-carboxylic acid
775354-21-7

(S)-1-((S)-2-tert-Butoxycarbonylamino-2-cyclohexyl-acetyl)-pyrrolidine-2-carboxylic acid

[2-({[(S)-1-((S)-2-tert-Butoxycarbonylamino-2-cyclohexyl-acetyl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid

[2-({[(S)-1-((S)-2-tert-Butoxycarbonylamino-2-cyclohexyl-acetyl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid

Conditions
ConditionsYield
With benzotriazol-1-ol; N-(3-dimethylaminopropyl)-N-ethylcarbodiimide; N-ethyl-N,N-diisopropylamine In dichloromethane
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

[2-({[(S)-1-((R)-3-Amino-4-phenyl-butyryl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid; compound with trifluoro-acetic acid

[2-({[(S)-1-((R)-3-Amino-4-phenyl-butyryl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid; compound with trifluoro-acetic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: EDC; HOBt; DIEA / CH2Cl2
2: CH2Cl2
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

[2-({[(S)-1-((S)-2-Amino-2-cyclohexyl-acetyl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid; compound with trifluoro-acetic acid

[2-({[(S)-1-((S)-2-Amino-2-cyclohexyl-acetyl)-pyrrolidine-2-carbonyl]-amino}-methyl)-phenyl]-acetic acid; compound with trifluoro-acetic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: EDC; HOBt; DIEA / CH2Cl2
2: CH2Cl2
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

3-methylisoquinoline
1125-80-0

3-methylisoquinoline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous alkaline solution
2: soda lime / 250 °C / mehrtaegiges Aufbewahren der bei 94-96grad/5 Torr siedenden Fraktion des Rktprod.
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

3-n-propylisoquinoline
76039-79-7

3-n-propylisoquinoline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous alkaline solution
2: soda lime / 250 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

3-methyl-1,2-dihydro-isoquinoline
59816-89-6

3-methyl-1,2-dihydro-isoquinoline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous alkaline solution
2: soda lime / 200 - 250 °C
View Scheme
triethylamine (TEA) hydrochloride

triethylamine (TEA) hydrochloride

4,4,4-trichloro-2-butanone
112605-39-7

4,4,4-trichloro-2-butanone

2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

α-(2-aminomethyl-1,4-cyclohexadienyl)acetic acid
56167-90-9

α-(2-aminomethyl-1,4-cyclohexadienyl)acetic acid

Conditions
ConditionsYield
With lithium In P2 O5; methanol hydrate
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(9H-fluoren-9-yl)methyl (2-(2-((2-hydroxyethyl)amino)-2-oxoethyl)benzyl)carbamate

(9H-fluoren-9-yl)methyl (2-(2-((2-hydroxyethyl)amino)-2-oxoethyl)benzyl)carbamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate / 1,4-dioxane; water / 2 h / 20 °C
2: 1-[(1-(cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino)]-uronium hexafluorophosphate; triethylamine / N,N-dimethyl-formamide / 1 h / 20 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(9H-fluoren-9-yl)methyl (2-(2-oxo-2-((2-oxoethyl)amino)ethyl)benzyl)carbamate

(9H-fluoren-9-yl)methyl (2-(2-oxo-2-((2-oxoethyl)amino)ethyl)benzyl)carbamate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: potassium carbonate / 1,4-dioxane; water / 2 h / 20 °C
2: 1-[(1-(cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino)]-uronium hexafluorophosphate; triethylamine / N,N-dimethyl-formamide / 1 h / 20 °C
3: Dess-Martin periodane / dichloromethane / 2 h / 20 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(9H-fluoren-9-yl)methyl (2-(oxazol-2-ylmethyl)benzyl)carbamate

(9H-fluoren-9-yl)methyl (2-(oxazol-2-ylmethyl)benzyl)carbamate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: potassium carbonate / 1,4-dioxane; water / 2 h / 20 °C
2: 1-[(1-(cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino)]-uronium hexafluorophosphate; triethylamine / N,N-dimethyl-formamide / 1 h / 20 °C
3: Dess-Martin periodane / dichloromethane / 2 h / 20 °C
4: Burgess Reagent / tetrahydrofuran / 12 h / 65 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

(2-(oxazol-2-ylmethyl)phenyl)methanamine

(2-(oxazol-2-ylmethyl)phenyl)methanamine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: potassium carbonate / 1,4-dioxane; water / 2 h / 20 °C
2: 1-[(1-(cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino)]-uronium hexafluorophosphate; triethylamine / N,N-dimethyl-formamide / 1 h / 20 °C
3: Dess-Martin periodane / dichloromethane / 2 h / 20 °C
4: Burgess Reagent / tetrahydrofuran / 12 h / 65 °C
5: piperidine / 1,4-dioxane / 1 h / 50 °C
View Scheme
2-Aminomethylphenylacetic acid
40851-65-8

2-Aminomethylphenylacetic acid

6-methyl-N-(2-(oxazol-2-ylmethyl)benzyl)-4-oxo-3,4-dihydrofuro[2,3-d]pyrimidine-5-carboxamide

6-methyl-N-(2-(oxazol-2-ylmethyl)benzyl)-4-oxo-3,4-dihydrofuro[2,3-d]pyrimidine-5-carboxamide

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: potassium carbonate / 1,4-dioxane; water / 2 h / 20 °C
2: 1-[(1-(cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholino)]-uronium hexafluorophosphate; triethylamine / N,N-dimethyl-formamide / 1 h / 20 °C
3: Dess-Martin periodane / dichloromethane / 2 h / 20 °C
4: Burgess Reagent / tetrahydrofuran / 12 h / 65 °C
5: piperidine / 1,4-dioxane / 1 h / 50 °C
6: 2-chloro-1,3-dimethylimidazolinium chloride; triethylamine / dichloromethane / 12 h / 20 °C
View Scheme

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