409064-76-2

Upstream product

• 146916-76-9 5-(4-methoxyphenyl)methoxy-2-pentyn-1-ol 
• 218434-90-3 1-but-3-ynyloxymethyl-4-methoxy-benzene 

Downstream Products

• 204447-27-8 2-[(Z)-3-Iodo-5-(4-methoxy-benzyloxy)-pent-2-enyloxy]-tetrahydro-pyran 
• 204447-34-7 (4R,5R)-5-[(Z)-8-(2-Heptyl-[1,3]dioxolan-2-yl)-oct-1-enyl]-4-[2-(4-methoxy-benzyloxy)-ethyl]-4-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxane 
• 204447-36-9 {(4R,5R)-4-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-5-[(Z)-8-(2-heptyl-[1,3]dioxolan-2-yl)-oct-1-enyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-methanol 

Relevant academic research and scientific papers

Synthesis of viridiofungin A trimethyl ester and determination of the absolute structure of viridiofungin A

Four diastereoisomeric trimethyl esters of viridiofungin A, a member of novel family of aminoacyl alkyl citrate compounds, were synthesized in a highly stereoselective manner and the absolute configuration of natural viridiofungin A was determined to be 3S,4S,2'S.

Total synthesis of malagashanine: a chloroquine potentiating indole alkaloid with unusual stereochemistry

The first total synthesis of malagashanine, a chloroquine potentiating indole alkaloid, is presented. A highly stereoselective cascade annulation reaction was developed to generate the tetracyclic core of the Malagasy alkaloids. This chemistry is likely to be broadly applicable to the synthesis of other members of this stereochemically unique family of natural products.