146916-76-9

Upstream product

• 38996-32-6 5-(tetrahydropyran-2-yloxy)-3-pentyn-1-ol 
• 824-94-2 p-methoxybenzyl chloride 
• 50-00-0 formaldehyd 
• 218434-90-3 1-but-3-ynyloxymethyl-4-methoxy-benzene 
• 2746-25-0 p-Methoxybenzyl bromide 

Downstream Products

• 853296-69-2 1-methoxycarbonyloxy-5-(4-methoxybenzyloxy)-2-pentyne 
• 444809-59-0 (2S,3R)-2-Chloromethyl-3-[2-(4-methoxy-benzyloxy)-ethyl]-oxirane 
• 855855-53-7 tert-butyl-{1-[2-(4-methoxy-benzyloxy)-ethyl]-prop-2-ynyloxy}-dimethyl-silane 
• 954134-47-5 C₃₁H₄₈O₉Si 
• 954134-51-1 C₃₁H₅₀O₉Si 
• 954134-26-0 C₂₇H₄₄O₇Si 
• 242808-65-7 ((2R,3R)-3-(2-(4-methoxybenzyloxy)ethyl)oxiran-2-yl)methanol 
• 444809-61-4 (3R)-5-[(4-methoxyphenyl)methoxy]pent-1-yn-3-ol 
• 126655-21-8 7-epi-australine 
• 146986-42-7 ((2S,3S)-3-(2-(4-methoxybenzyloxy)ethyl) oxiran-2-yl)methanol 
• 459870-75-8 6-(4-methoxyphenyl)methoxy-3,4-epoxy-1-hexene 
• 618384-67-1 (1S,2R,3R,7R,7aR)-3-Benzyloxymethyl-hexahydro-pyrrolizine-1,2,7-triol 
• 618384-82-0 (1R,2R,3R,7R,7aR)-3-Benzyloxymethyl-hexahydro-pyrrolizine-1,2,7-triol 
• 618384-64-8 (2R,3R,4S,5R)-2-Benzyloxymethyl-5-((R)-1,3-dihydroxy-propyl)-pyrrolidine-3,4-diol 

Relevant academic research and scientific papers

Asymmetric synthesis of ( - )-7-epiaustraline and (+)-1,7-diepiaustraline

A diastereoselective and modular approach to the synthesis of the 3-hydroxymethyl-2,3,5,6,7,7a-hexahydro-1H-pyrrolizine-1,2,7-triol structure, characteristic of several natural pyrrolizidine natural products, has been developed. This approach culminated i

Stereoselective Synthesis of the C(1)?–?C(28) Fragment of Amphidinol 3

A stereoselective synthesis of the polyol side chain (C(1)?–?C(28)) of amphidinol 3 has been accomplished following Sharpless epoxidation, Crimmins aldol reaction, Jacobsen kinetic resolution, Sharpless asymmetric dihydroxylation, and our own reaction for

Asymmetric syntheses of all stereoisomers of 3-hydroxyproline; A constituent of several bioactive compounds

Synthesis of an unusual β-hydroxy-α-amino acid, 3-hydroxyproline, and its derivatives have been achieved enantioselectively by employing Sharpless asymmetric epoxidation and reductive cyclization as the key steps. Georg Thieme Verlag Stuttgart ? New York.

Stereoconvergent synthesis of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A

Stereoconvergent syntheses of the C1-C11 and C12-C24 fragments of (-)-macrolactin-A are reported.

A convergent approach for the total synthesis of (-)-synrotolide diacetate

A simple carbohydrate based convergent approach towards the total synthesis of (-)-synrotolide diacetate is described employing a Sharpless asymmetric epoxidation, a Grignard assisted lactol opening with a terminal alkyne and a Wittig reaction using the H

A new convergent and stereoselective synthesis of 2,5-disubstituted N-acylpyrrolidines

A new synthesis of 2,5-disubstituted N-acylpyrrolidines through an SN2′ reaction promoted by the nitrogen anion of a secondary amide onto an allylic bromide is reported. A moderate stereoselectivity, in favour of the trans heterocycle, was obse

Synthesis of viridiofungin A trimethyl ester and determination of the absolute structure of viridiofungin A

Four diastereoisomeric trimethyl esters of viridiofungin A, a member of novel family of aminoacyl alkyl citrate compounds, were synthesized in a highly stereoselective manner and the absolute configuration of natural viridiofungin A was determined to be 3S,4S,2'S.

Studies Directed Towards the Total Synthesis of Rhizoxin: Stereoselective Synthesis of C-12 to C-18 Segment

Chiral carbinol 5, made by a titanocene mediated ring opening of epoxy alcohol 11, was converted via an intramolecular radical cyclisation into a 'butanolide template' which was then transformed to the C-12 to C-18 segment 2 of rhizoxin (1). Key Words: Butanolide chiral template; Chiral carbinol; Intramolecular radical cyclisation; Vinyl Grignard reaction.