409360-86-7Relevant academic research and scientific papers
Stereoselective Construction of Entire Diastereomeric Stereotetrads Based on an Asymmetric Morita–Baylis–Hillman Reaction
Yoshimura, Hikaru,Ishihara, Jun,Hatakeyama, Susumi
, p. 2719 - 2729 (2017/05/29)
A method for the enantio- and diastereoselective construction of all possible stereoisomers of a polypropionate stereotetrad having four contiguous stereogenic centers has been developed. The approach features an iterative sequence of cinchona-alkaloid-ca
Superior substrate control on diastereoselection in boric Lewis acid-promoted aldol reactions. Asymmetric synthesis of a 3,4-syn homologous series of ethyl 3,5-dihydroxy-2,4-dimethyl-5-phenylpentanoates
Kiyooka, Syun-ichi,Shahid, Kazi A.,Murai, Kazunori,Li, Yong-Nan,Okazaki, Momotoshi,Shuto, Yoshihiro
, p. 2343 - 2349 (2007/10/03)
The BF3·OEt2-promoted aldol reaction of chiral syn- and anti-α-methyl-β-siloxy aldehydes with a silyl ketene acetal resulted in essentially complete syn Felkin selection. Even in the asymmetric aldol reaction using chiral oxazaboroli
