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4098-15-1

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4098-15-1 Usage

General Description

1-(2-iodo-1,2-diphenylethyl)triaza-1,2-dien-2-ium is a chemical compound with a formula C23H20IN3. It belongs to the category of triaza dienes, which are organic compounds containing a triazadiene skeleton, a six-membered ring with two nitrogen atoms, and a double bond. This particular compound contains an iodo substituent and a diphenylethyl group, giving it specific chemical properties and potential applications. As a triaza dienium salt, it is often used as a reactant in organic synthesis and can participate in various reactions, such as nucleophilic additions and substitution reactions. Its structure and reactivity make it a potentially useful building block for creating more complex organic compounds in chemical research and industry.

Check Digit Verification of cas no

The CAS Registry Mumber 4098-15-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,0,9 and 8 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 4098-15:
(6*4)+(5*0)+(4*9)+(3*8)+(2*1)+(1*5)=91
91 % 10 = 1
So 4098-15-1 is a valid CAS Registry Number.

4098-15-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name imino-(2-iodo-1,2-diphenylethyl)iminoazanium

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4098-15-1 SDS

4098-15-1Relevant articles and documents

A Smooth and Practicable Azido-Iodination Reaction of Alkenes Based on IPy2BF4 and Me3SiN3

Barluenga, Jose,Alvarez-Perez, Monica,Fananas, Francisco J.,Gonzalez, Jose M.

, p. 335 - 337 (2001)

The reaction of alkenes with IPy2BF4 and Me3SiN3 under the influence of BF3 · OEt2 provides a mild an efficient entry to vicinal azidoiodoalkanes. Besides the simplicity of the experimental protocol and the convenience found in the handling of the reagents, the use of stoichiometric amounts of the azide source is remarkable, and overrides the known and always troublesome dependence on large excesses of azide to accomplish this synthetically valuable transformation.

A sustainable strategy for the straightforward preparation of 2H-azirines and highly functionalized NH-aziridines from vinyl azides using a single solvent flow-batch approach

Andresini, Michael,Degannaro, Leonardo,Luisi, Renzo

supporting information, p. 203 - 209 (2021/02/26)

The reported flow-batch approach enables the easy preparation of 2H-azirines and their stereoselective transformation into highly functionalized NH-aziridines, starting from vinyl azides and organolithium compounds. The protocol has been developed using c

Photoswitchable Regiodivergent Azidation of Olefins with Sulfonium Iodate(I) Reagent

Rao, Dodla S.,Reddy, Thurpu R.,Gurawa, Aakanksha,Kumar, Manoj,Kashyap, Sudhir

supporting information, p. 9990 - 9994 (2019/12/02)

Photoswitchable strategy for selective azidation of structurally diverse olefins under transition-metal-free conditions is reported. The unprecedented reactivity of trimethylsulfonium [bis(azido)iodate(I)] species under visible light allows radical azidooxygenation of the C═C πbond with distinctive selectivity. In the absence of visible light, the reaction proceeds through an ionic intermediate which led to complementary regioselectivity to provide α-alkyl azides. Mechanistic studies reveal that light-controlled regiodivergent azidation involving radical or an ionic pathway can be accomplished with exclusive regioselectivity.

Photoredox-catalysed redox-neutral trifluoromethylation of vinyl azides for the synthesis of α-trifluoromethylated ketones

Qin, Hai-Tao,Wu, Shu-Wei,Liu, Jia-Li,Liu, Feng

supporting information, p. 1696 - 1699 (2017/02/10)

A redox-neutral, mild, and simple protocol is developed for the synthesis of α-trifluoromethylated ketones from vinyl azides under transition-metal-free conditions. In the presence of organic photoredox catalyst N-methyl-9-mesityl acridinium and sodium trifluoromethanesulfinate, a broad range of substituted vinyl azides were found to react smoothly upon visible-light irradiation, readily furnishing the corresponding products in satisfied yields.

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