40995-25-3Relevant academic research and scientific papers
N-arylation of 1-aminobenzimidazole
Pozharskii,Dyablo,Kuz'menko,Evgrafova
, p. 1156 - 1159 (2007/10/03)
By treatment of the sodium (potassium) salt of 1-formylaminobenzimidazole in acetone or DMF with picryl chloride, 2,4-dinitrochlorobenzene, 2- and 4-nitrochlorobenzenes, we obtained the corresponding 1-arylaminobenzimidazoles. This is the first case of direct arylation of the amino group in N-aminobenzimidazole. 1997 Plenum Publishing Corporation.
METALLATION OF 1-DIALKYLAMINOBENZIMIDAZOLES
Kuz'menko, V. V.,Filatova, I. A.,Pozharskii, A. F.
, p. 1009 - 1014 (2007/10/02)
In contrast to 1-amino- and 1-alkylaminobenzimidazoles, 1-di-alkylaminobenzimidazoles are metallated by n-butyl-lithium in absolute ether at the 2-position.The subsequent treatment of the lithium derivatives by electrophilic reagents, in which role benzop
