41013-29-0

Basic information

• Product Name: N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine
• CAS NO: 41013-29-0
• Molecular Weight: 420.511
• Mol File: 41013-29-0.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine(41013-29-0)
• EPA Substance Registry System: N,N'-bis(salicylaldehyde)trans-1,2-diphenylethylenediimine(41013-29-0)

Safety Data

• Hazardous Substances Data: 41013-29-0(Hazardous Substances Data)

Upstream product

• 5700-60-7 1,2-Diphenylethylenediamine 
• 90-02-8 salicylaldehyde 
• 951-87-1 rac-1,2-diphenylethylene-1,2-diamine 
• 123-54-6 acetylacetone 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 119386-71-9 2,2’-((1R,2R)-1,2-diaminoethane-1,2-diyl)diphenol 
• 100-52-7 benzaldehyde 
• 89-95-2 2-methyl-benzyl alcohol 
• 29841-69-8 (S,S)-1,2-diphenyl-1,2-diaminoethane 
• 951-87-1 meso-1,2-diphenyl-1,2-diaminoethane 
• 58519-80-5 meso-1,2-bis(2-hydroxyphenyl)-1,2-ethylenediamine 
• 119386-71-9 (SR,SR)-1,2-di-(2-hydroxyphenyl)-1,2-diaminoethane 
• 14371-10-9 (E)-3-phenylpropenal 
• 617-35-6 2-oxo-propionic acid ethyl ester 

Downstream Products

• 951-87-1 meso-1,2-diphenyl-1,2-diaminoethane 
• 84995-07-3 meso-2,2'-<(1,2-diphenylethylene)bis(iminomethylene)>diphenol 
• 3190-01-0 meso-α.α'-bis-benzylidenamino-bibenzyl 
• 951-87-1 rac-1,2-diphenylethylene-1,2-diamine 
• 51922-39-5 meso-N,N'-((E,E)-dibenzylidene)-bibenzyl-α,α'-diyldiamine 
• 3190-01-0 racem-N,N'-dibenzylidene-bibenzyl-α,α'-diyldiamine 
• 3190-01-0 N,N'-dibenzylidene-1,2-diphenylethane-1,2-diamine 
• 278803-40-0 oxo (disalicylidene (1,2-diphenyl ethylene diamine)) vanadium (IV) 
• 149580-33-6 chloro-[N,N'-bis(salicylidene)-1,2-diphenylethylenediaminato]manganese(III) 
• 897628-12-5 (C₆H₄(O)CHNCH(C₆H₅)CH(C₆H₅)NCHC₆H₄(O))CrCl 

Relevant articles and documents

Three-Way Chemoselectivity Switching through Coupled Equilibria

Controlling the chemoselectivity of reactions operating on complex mixtures, including those found in biological and petrochemical feedstocks or in the primordial soup from which life emerged, is generally challenging. The selectivity of imine oxidation c

Palladium (II)–Salan Complexes as Catalysts for Suzuki–Miyaura C–C Cross-Coupling in Water and Air. Effect of the Various Bridging Units within the Diamine Moieties on the Catalytic Performance

Water-soluble salan ligands were synthesized by hydrogenation and subsequent sulfonation of salens (N,N’-bis(slicylidene)ethylenediamine and analogues) with various bridging units (linkers) connecting the nitrogen atoms. Pd (II) complexes were obtained in reactions of sulfosalans and [PdCl4]2?. Characterization of the ligands and complexes included extensive X-ray diffraction studies, too. The Pd (II) complexes proved highly active catalysts of the Suzuki–Miyaura reaction of aryl halides and arylboronic acid derivatives at 80 ?C in water and air. A comparative study of the Pd (II)–sulfosalan catalysts showed that the catalytic activity largely increased with increasing linker length and with increasing steric congestion around the N donor atoms of the ligands; the highest specific activity was 40,000 (mol substrate) (mol catalyst × h)?1. The substrate scope was explored with the use of the two most active catalysts, containing 1,4-butylene and 1,2-diphenylethylene linkers, respectively.

Chiral and non-conjugated fluorescent salen ligands: AIE, anion probes, chiral recognition of unprotected amino acids, and cell imaging applications

Natural products are usually non-conjugated and chiral, but organic luminescent materials are commonly polycyclic aromatic molecules with extended π-conjugation. In the present work, we combine with the advantages of non-conjugation and chirality to prepare a series of novel and simple salen ligands (41 samples), which have a non-conjugated and chiral (S,S) and (R,R) cyclohexane or 1,2-diphenylethane bridge but display strong blue, green, and red aggregation-induced emission (AIE) with large Stokes shifts (up to 186 nm) and high fluorescence quantum yields (up to 0.35). Through hydrogen and halogen bonds, these flexible salen ligands can be used as universal anion probes and chiral receptors of unprotected amino acids (enantiomeric selectivity up to 0.11) with fluorescence quantum yields up to 0.29 and 0.27, respectively. Moreover, the effects of different chiral bridges on the molecule arrangement, AIE, and anion and chiral recognition properties are also explored, which provide unequivocal insights for the design of non-conjugated chiral and soft fluorescent materials.