4111-61-9Relevant academic research and scientific papers
Enantioselective halogenative semi-pinacol rearrangement: A stereodivergent reaction on a racemic mixture
Romanov-Michailidis, Fedor,Pupier, Marion,Gune, Laure,Alexakis, Alexandre
supporting information, p. 13461 - 13464 (2015/02/19)
An efficient, quantitative deracemization strategy for optically inactive allylic cycloalkanols has been achieved using the biphasic halogenative semi-pinacol reaction protocol. The resultant β-halo spiroketones, containing three contiguous stereogenic ce
'Me2CuLi·TMSCl in CH2Cl2'. The most powerful methylating agent for sterically congested α,β-enoates
Asao, Naoki,Lee, Sunyoung,Yamamoto, Yoshinori
, p. 4265 - 4266 (2007/10/03)
The reaction of Me2CuLi with sterically congested α,β-unsaturated esters in the presence of TMSCl in CH2Cl2 proceeded very smoothly to produce the conjugate addition products in high yields.
Enantioselective Protonation of Samarium Enolates by a C2-Symmetric Chiral Diol
Takeuchi, Seiji,Ohira, Akiko,Miyoshi, Norikazu,Mashio, Hajime,Ohgo, Yoshiaki
, p. 1763 - 1780 (2007/10/02)
High enantioselectivity (up to 97percentee) have been achieved in the protonation of samarium enolates which were generated by SmI2-mediated cross-coupling reaction between unsymmetrical dialkylketene and allyl iodide, using, using a C2-symmetr
