4114-99-2

Basic information

• Product Name: 3-Cycloocten-1-ol
• Synonyms: 3-Cycloocten-1-ol
• CAS NO: 4114-99-2
• Molecular Formula: C₈H₁₄O
• Molecular Weight: 0
• Mol File: 4114-99-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cycloocten-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cycloocten-1-ol(4114-99-2)
• EPA Substance Registry System: 3-Cycloocten-1-ol(4114-99-2)

Safety Data

• Hazardous Substances Data: 4114-99-2(Hazardous Substances Data)

Upstream product

• 1073-07-0 1,4-cyclooctadiene 
• 286-62-4 Cyclooctene oxide 
• 73982-04-4 cis-1,4-dihydroxycyclooctane 

Downstream Products

• 1580502-02-8 C₁₅H₁₇NO₅ 
• 20731-23-1 methyl non-8-enoate 
• 94-66-6 2-allylcyclohexan-1-one 
• 4884-99-5 3-Methoxy-cyclooctanon-(2.4-dinitro-phenylhydrazon) 
• 132637-53-7 N-(cyclo-oct-3-enyl)-N'-p-tosylhydrazine 
• 23691-50-1 cyclo-oct-3-enone p-tosylhydrazone 
• 117409-77-5 10,11,12,13-Tetraphenyl-3-oxatricyclo<7.4.0.0^2,4>trideca-1(9),10,12-trien 
• 29077-87-0 9-oxa-bicyclo[6.1.0]nonan-3-ol 
• 29077-87-0 3,4-epoxycyclooctanol 
• 1152315-48-4 9-Oxa-bicyclo[6.1.0]nonan-3-ol 

Relevant articles and documents

Isomerization of Cyclooctene and Cyclododecene Oxides Catalyzed by Solid Acids and Bases

The title reactions were carried out over seven catalysts.From cyclooctene oxide a large amount of 7-octenal was formed together with 3-cycloocten-1-ol over SiO2-Al2O3 and SiO2-TiO2, 3-cycloocten-1-ol over solid H3PO4, and cyclooctanone over FeSO4.Most catalysts except for NiSO4, Al2O3, and Tio2-ZrO2 produced 1,3-cyclododecadiene, cyclododecanone, and 2-cyclododecen-1-ol uniformly from cyclododecene oxide.Allylic alcohols were preferentially given by Al2O3 and TiO2-ZrO2.

Displacement Stereochemistry and Product-Formation Selectivities in the Solvolysis of Cyclooctyl p-Bromobenzenesulfonate

Configurational analysis by 2H NMR of the products of solvolysis of (E)-cyclooctyl-2-d and (E)-cyclooctyl-4-d brosylate in acetic acid and 80percent acetone has established that substitution without rearrangement occurs with complete retention of configuration while substitution under 1,5-hydride shift takes place with complete inversion at the migration origin.The reaction is concluded to proceed by direct initial formation of a 1,5-hydrogen-bridged cation.Solvolysis of cyclooctyl-1-d brosylate in several solvents has shown elimination to be favored from C-1 over the C-5 side, whereas selectivities for competitive substitutions are similar at the two positions.Elimination is thus indicated to take place largely from first-formed tight ion pairs while displacement proceeds through more dissociated intermediates.

Oxymetallation. Part 13. Synthesis of Bicyclic Peroxides via Peroxymercuriation of Cyclic Dienes

The bis-mercuriated derivative (12) of 9,10-dioxabicyclodecane has been prepared by peroxymercuriation of cis,cis-octa-1,5-diene, but substantial amounts of bicyclic ethers are also formed in the reaction.The bicyclic peroxides (4) and (5) have been obtained from (12) by reduction and brominolysis respectively. 8,9-Dioxabicyclodecane (6) and the dibromo-derivative (7) have similarly been prepared by peroxymercuriation and demercuriation of cyclo-octa-1,4-diene.It is suggested that the isomeric purity of the peroxides and the concurrent formation of bicyclic ethers both result from equilibrium control of reversible (per)oxymercuriation-de(per)oxymercuriation.A low yield of the -peroxide (8) has been obtained by peroxymercuriation and brominolysis of cyclohexa-1,4-diene, but attempts to prepare -compounds from 5,5-disubstituted cyclopentadienes have been unsuccessful.