41159-12-0Relevant articles and documents
Selective arylthiolane deprotection by singlet oxygen: A promising tool for sensors and prodrugs
Lamb, Brian M.,Barbas, Carlos F.
, p. 3196 - 3199 (2015)
A routine thioketal protecting group reacts rapidly and selectively with singlet oxygen to reveal ketone products in good (aryl 1,3-dithiolane) to excellent (aryl 1,3-oxathiolane) yields. Arylthiolanes are stable to biologically relevant reactive oxygen species and can be used as a light-activated gating mechanism for activating fluorescent sensors or small molecule prodrugs.
An efficient, continuous flow technique for the chemoselective synthesis of thioacetals
Wiles, Charlotte,Watts, Paul,Haswell, Stephen J.
, p. 7362 - 7365 (2008/03/13)
By optimizing a reagent's residence time within a packed-bed reactor, it is possible to overcome selectivity issues frequently encountered in stirred reaction vessels. This important feature is demonstrated for the chemoselective protection of 4-acetylben
An efficient method for the thioacetalization of carbonyl compounds in the presence of catalytic amounts of benzyltriphenylphosphonium tribromide
Hajipour,Pourmousavi,Ruoho
, p. 403 - 412 (2008/02/09)
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