41177-03-1

Basic information

• Product Name: (4-methyl-cyclohexyl)-carbamic acid methyl ester
• Synonyms: (4-methyl-cyclohexyl)-carbamic acid methyl ester
• CAS NO: 41177-03-1
• Molecular Weight: 171.239
• Mol File: 41177-03-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4-methyl-cyclohexyl)-carbamic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methyl-cyclohexyl)-carbamic acid methyl ester(41177-03-1)
• EPA Substance Registry System: (4-methyl-cyclohexyl)-carbamic acid methyl ester(41177-03-1)

Safety Data

• Hazardous Substances Data: 41177-03-1(Hazardous Substances Data)

Upstream product

• 106-49-0 p-toluidine 
• 616-38-6 carbonic acid dimethyl ester 
• 124-41-4 sodium methylate 

Downstream Products

• 6321-23-9 4-methylcyclohexylamine 

Relevant articles and documents

Ruthenium-Na2CO3-catalyzed one-pot synthesis of ring-hydrogenated carbamates from aromatic amines and organic carbonates under H2

A facile and efficient one-pot procedure for the synthesis of ring hydrogenated carbamates from aromatic amine and alkylene carbonate under H2 gas pressure has been developed using a heterogeneous catalyst system comprising ruthenium and alkali metal carbonates. The effects of temperature, H2 pressure, catalyst (types of loaded metal and their supports), molar ratio of substrate/catalyst, and solvent were also investigated. Among the alkali metal carbonates, the sodium carbonate was found as best promoter for nucleophilic attack and ring-opening (NARO) reaction and thus increased the yield of ring hydrogenated carbamate up to 88% when using Ru/C as ring hydrogenation (RH) catalyst. This catalyst system could be reused at least five times without signi?cant loss of activity, which makes this process cost-effective and eco-friendly.