412270-77-0Relevant academic research and scientific papers
Highly efficient synthesis of terminal alkenes from ketones
Lebel, Helene,Guay, Danielle,Paquet, Valerie,Huard, Kim
, p. 3047 - 3050 (2004)
(Chemical Equation Presented) The rhodium(I)-catalyzed methylenation of ketones using trimethylsilyldiazomethane proceeds to give the corresponding alkenes in good yields (60-97%). The use of an excess of 2-propanol and 1,4-dioxane as a solvent were instr
Rhodium-catalyzed synthesis of terminal alkenes
Paquet, Valerie,Lebel, Helene
, p. 1901 - 1905 (2007/10/03)
Terminal alkenes have been efficiently prepared via a rhodium-catalyzed olefination procedure using Wilkinson's catalyst in the presence of triphenylphosphine, 2-propanol and trimethylsilyldiazomethane. Optimized reaction conditions are described for aldehydes and ketones, as well as alternative work up procedures. Georg Thieme Verlag Stuttgart.
