2-(triisopropylsilanyloxy)cyclohexylmethylene

Base Information

• Chemical Name: 2-(triisopropylsilanyloxy)cyclohexylmethylene
• CAS No.: 412270-77-0
• Molecular Formula: C₁₆H₃₂OSi
• Molecular Weight: 268.515
• Mol file: 412270-77-0.mol

Synonyms:2-(triisopropylsilanyloxy)cyclohexylmethylene

Chemical Property of 2-(triisopropylsilanyloxy)cyclohexylmethylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(triisopropylsilanyloxy)cyclohexylmethylene

There total 2 articles about 2-(triisopropylsilanyloxy)cyclohexylmethylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2-(triisopropylsilanyloxy)cyclohexanone (296229-06-6) + diazomethyl-trimethyl-silane (18107-18-1) → 2-(triisopropylsilanyloxy)cyclohexylmethylene (412270-77-0)

Guidance literature:

With triphenylphosphine; isopropyl alcohol; Wilkinson's catalyst; In 1,4-dioxane; at 60 ℃; for 4h;

DOI:10.1021/ol049085p

Reference yield: 34.0%

Methyltriphenylphosphonium bromide (1779-49-3) + 2-(triisopropylsilanyloxy)cyclohexanone (296229-06-6) → 2-(triisopropylsilanyloxy)cyclohexylmethylene (412270-77-0)

Guidance literature:

Methyltriphenylphosphonium bromide; With lithium hexamethyldisilazane; In 1,4-dioxane; at 60 ℃; for 1h;

2-(triisopropylsilanyloxy)cyclohexanone; In 1,4-dioxane; at 60 ℃; for 4h;

DOI:10.1021/ol049085p

Reference yield:

carbon monoxide (201230-82-2) + 2-(triisopropylsilanyloxy)cyclohexylmethylene (412270-77-0) → (2-triisopropylsilanyloxy-cyclohexyl)-acetaldehyde

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; hydrogen; In benzene; at 20 ℃; under 51716.2 Torr;

DOI:10.1021/jo001751m

upstream raw materials:

2-(triisopropylsilanyloxy)cyclohexanone

diazomethyl-trimethyl-silane

Methyltriphenylphosphonium bromide