412313-45-2Relevant academic research and scientific papers
TRIMETHYLCHOLOROSILANE INDUCED RING OPENING OF 2-ALKYLOXAZOLIDINES TO ENAMINE DERIVATIVES
Ito, Yoshihiko,Sawamura, Masaya,Kominami, Kazuhiko,Saegusa, Takeo
, p. 5303 - 5306 (2007/10/02)
2-Alkyloxazolidines (5) were ring-opened by trimethylchlorosilane with N,N-diisopropylamine to give N--enamines (6).A MgCl2 promoted Michael reaction of chiral enamines thus prepared was achieved with asymmetric induction.
