4125-54-6

Basic information

• Product Name: Acetic acid 2-allylphenyl ester
• Synonyms: 2-Allylphenol acetate;Acetic acid 2-allylphenyl ester;(2-prop-2-enylphenyl) acetate;(2-prop-2-enylphenyl) ethanoate
• CAS NO: 4125-54-6
• Molecular Formula: C₁₁H₁₂O₂
• Molecular Weight: 176.22
• Mol File: 4125-54-6.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 256.1°C at 760 mmHg
• Flash Point: 96.9°C
• Appearance: /
• Density: 1.027g/cm³
• Vapor Pressure: 0.0157mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: Acetic acid 2-allylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid 2-allylphenyl ester(4125-54-6)
• EPA Substance Registry System: Acetic acid 2-allylphenyl ester(4125-54-6)

Safety Data

• Hazardous Substances Data: 4125-54-6(Hazardous Substances Data)

Usage

General Description

Acetic acid 2-allylphenyl ester, also known as allyl phenyl acetate, is a clear, colorless liquid with a sweet, floral odor. It is commonly used in the production of perfumes and as a flavoring agent in food and beverages. Chemically, it is an ester formed from acetic acid and allyl phenol, and it is often found naturally in fruits and essential oils. It is also used in the manufacture of pharmaceuticals and as a solvent for various organic compounds. However, it is important to handle this chemical with care, as it can be irritating to the skin, eyes, and respiratory system, and can also be harmful if ingested.

InChI:InChI=1/C11H12O2/c1-3-6-10-7-4-5-8-11(10)13-9(2)12/h3-5,7-8H,1,6H2,2H3

Upstream product

• 108-24-7 acetic anhydride 
• 1745-81-9 o-Allylphenol 
• 75-36-5 acetyl chloride 

Downstream Products

• 1746-11-8 2-methyl-2,3-dihydro-1-benzofuran 
• 55693-05-5 1-Cyclopentyl-4-(2-hydroxy-phenyl)-butan-1-one 
• 55693-04-4 Acetic acid 2-(4-cyclopentyl-4-oxo-butyl)-phenyl ester 
• 36339-67-0 2-(2'-chloro-3'-perfluorooctyl)-n-propylphenyl acetate 
• 1210066-82-2 (E)-3-(2-acetoxyphenyl)allyl propionate 
• 106492-61-9 2-Allyl-6-nitrophenyl acetate 
• 35922-87-3 acetic acid trans-2-(1-propenyl)phenyl ester 
• 33538-94-2 (E)-2-(3-oxoprop-1-en-1-yl)phenyl acetate 
• 35922-83-9 o-propylphenyl acetate 
• 1444827-02-4 C₁₇H₂₃BO₄ 

Relevant articles and documents

Synthesis and in vitro growth inhibition of 2-allylphenol derivatives against Phythopthora cinnamomi rands

Phytophthora cinnamomi is a phytopathogen that causes extensive damage in different crops, and therefore, produces important economic losses all around the world. Chemical fungicides are a key factor for the control of this disease. However, ecological an

Chlorotrifluoromethylation of Terminal Olefins by Atom Transfer-Type Radical Reaction Catalyzed by Cobalt Complexes

A cobalt porphyrin-catalyzed chlorotrifluoromethylation reaction of olefins is described. The use of CF3SO2Cl as the CF3 radical source and a cobalt catalyst enabled the selective addition of CF3 radicals under thermal conditions. Various functional groups such as esters and Ar–X moieties, which can be reactive with low valent transition metal catalysts, were well-tolerated in this catalytic process. A highly functionalized alkaloid derivative was also tolerated as a substrate. As a demonstration of the bio-inspired catalytic system, catalytic usage of vitamin B12, which is the commercially available form of the natural cobalt porphyrinoid, was employed, and diastereoselective chlorotrifluoromethylation of the alkaloid molecule was achieved.

METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS

The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1:500 or less, and the conversion of the first or the second olefin to said olefin is at least 50%,characterized in that as compound that catalyzes said metathesis reaction a compound of the following formula is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6—X—, wherein X═O and R6 is aryl, optionally substituted; or X═S and R6 is aryl, optionally substituted; or X═O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X═O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.