41280-64-2

Basic information

• Product Name: 4-TERT-BUTYL-1,2-DIMETHOXYBENZENE
• Synonyms: 4-TERT-BUTYL-1,2-DIMETHOXYBENZENE;1,2-Dimethoxy-4-tert-butylbenzene;4-tert-Butylveratrole
• CAS NO: 41280-64-2
• Molecular Formula: C₁₂H₁₈O₂
• Molecular Weight: 194.27
• Mol File: 41280-64-2.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-TERT-BUTYL-1,2-DIMETHOXYBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-TERT-BUTYL-1,2-DIMETHOXYBENZENE(41280-64-2)
• EPA Substance Registry System: 4-TERT-BUTYL-1,2-DIMETHOXYBENZENE(41280-64-2)

Safety Data

• Hazardous Substances Data: 41280-64-2(Hazardous Substances Data)

Upstream product

• 65492-28-6 o-benzoquinone bis(dimethyl acetal) 
• 594-19-4 tert.-butyl lithium 
• 120-80-9 benzene-1,2-diol 
• 77-78-1 dimethyl sulfate 
• 75-65-0 tert-butyl alcohol 
• 98-29-3 4-tert-Butylcatechol 
• 91-16-7 1,2-dimethoxybenzene 
• 74-88-4 methyl iodide 
• 119090-58-3 2-chloro-5-t-butyl-1,3,2-benzodioxastibole 
• 100-58-3 phenylmagnesium bromide 
• 75-57-0 tetramethlyammonium chloride 
• 507-20-0 tertiary butyl chloride 
• 90-05-1 2-methoxy-phenol 
• 94264-86-5 1-benzyloxy-4-tert-butyl-2-methoxy-benzene 

Downstream Products

• 34582-09-7 1-bromo-2-(tert-butyl)-4,5-dimethoxybenzene 
• 1403878-94-3 C₃₁H₄₄O₅ 
• 1442465-80-6 (2E,5E)-2,5-bis(5-tert-butyl-2,3-dimethoxybenzylidene)cyclopentanone 
• 1442465-76-0 5-tert-butyl-2,3-dimethoxybenzaldehyde 
• 69770-00-9 5-tert-butyl-2-methoxyphenol 
• 37987-27-2 4-t-butyl-2-methoxyphenol 
• 98-29-3 4-tert-Butylcatechol 
• 1774-86-3 5-tert-butyl-2-methoxy-1,4- benzoquinone 

Relevant articles and documents

Direct Synthesis of Hydroquinones from Quinones through Sequential and Continuous-Flow Hydrogenation-Derivatization Using Heterogeneous Au–Pt Nanoparticles as Catalysts

Pt–Au bimetallic nanoparticle catalysts immobilized on dimethyl polysilane (Pt–Au/(DMPSi-Al2O3)) have been developed for selective hydrogenation of quinones to hydroquinones. High reactivity, selectivity, and robustness of the catalysts were confirmed under continuous-flow conditions. Various direct derivatizations of quinones, such as methylation, acetylation, trifluoromethanesulfonylation, methacrylation, and benzoylation were successfully performed under sequential and continuous-flow conditions to afford the desired products in good to excellent yields. Especially, air-sensitive hydroquinones, such as anthrahydroquinones and naphthohydroquinones, could be successfully generated and derivatized under closed sequential and continuous-flow conditions without decomposition.

Direct alkylation of aromatics using alcohols in the presence of NaHSO 4/SiO2

Simple and efficient procedure for alkylation of aromatics from alcohols in the presence of NaHSO4/SiO2 was developed. Various triaryl methanes were obtained in good yields in short reaction time. For instance the reaction of mesitylene with benzhydrol in the presence of NaHSO4/SiO2 gave the corresponding triaryl methane in a quantitative yield. NaHSO4/SiO2 was regenerated by simple treatment and could be recycled eight times without activity loss.

Nickel-catalyzed Kumada reaction of tosylalkanes with Grignard reagents to produce alkenes and modified arylketones

Open a new door: The first example of alkene synthesis from alkyl electrophiles with Grignard reagents using the Kumada cross-coupling reaction strategy is reported. This method opens a new door for the Kumada cross-coupling reaction, allowing alkenes to be prepared from the reaction of tosylalkanes with Grignard reagents. Copyright