413570-96-4Relevant academic research and scientific papers
The insertion of dimethyl acetylenedicarboxylate into an S-Pd bond
Sugoh, Kunihiko,Kuniyasu, Hitoshi,Kurosawa, Hideo
, p. 106 - 107 (2002)
The first definitive evidence of insertion of an alkyne into an S-Pd bond has been presented. The reaction of Pd(SAr)2(DPPE) with dimethyl acetylenedicarboxylate (DMAD) gave the cis-insertion product (Z)-Pd-[C(CO2Me) = C(SAr)(CO
